基于双氨基酸型组氨酸和二元羧酸的反式-顺式构型调控超分子聚合物凝胶及手性转移
trans-cis Configuration regulated supramolecular polymer gels and chirality transfer based on a bolaamphiphilic histidine and dicarboxylic acids.
作者信息
Chen Chunfeng, Wang Tianyu, Fu Yunzhi, Liu Minghua
机构信息
Department of Materials Science and Chemical Engineering, Hainan University, Haikou, P. R. China and Beijing National Laboratory for Molecular Science, CAS Key Laboratory of Colloid, Interface and Chemical Thermodynamics, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, P. R. China.
Beijing National Laboratory for Molecular Science, CAS Key Laboratory of Colloid, Interface and Chemical Thermodynamics, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, P. R. China.
出版信息
Chem Commun (Camb). 2016 Jan 25;52(7):1381-4. doi: 10.1039/c5cc09210h.
Supramolecular polymer gels based on the co-assembly of bolaamphiphilic l-histidine(BolaHis) and dicarboxylic acids are dependent on the molar ratios, flexibility and cis-trans configuration of acid molecules. Thus, oligomerized rigid cis-maleic acid or flexible trans-cyclohexane dicarboxylic acid can form chiral supramolecular polymer gels with l-BolaHis.
基于双嗜性 l-组氨酸（BolaHis）和二元羧酸共组装的超分子聚合物凝胶取决于酸分子的摩尔比、柔韧性和顺反构型。因此，低聚刚性顺式马来酸或柔性反式环己烷二甲酸可与 l-BolaHis 形成手性超分子聚合物凝胶。
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