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城市固体废弃物焚烧炉底灰对小麦(Triticum aestivum L.)种子萌发的植物毒性随淋溶条件的变化。

Variation of the phytotoxicity of municipal solid waste incinerator bottom ash on wheat (Triticum aestivum L.) seed germination with leaching conditions.

作者信息

Phoungthong Khamphe, Zhang Hua, Shao Li-Ming, He Pin-Jing

机构信息

State Key Laboratory of Pollution Control & Resource Reuse, Tongji University, Shanghai 200092, PR China.

State Key Laboratory of Pollution Control & Resource Reuse, Tongji University, Shanghai 200092, PR China.

出版信息

Chemosphere. 2016 Mar;146:547-54. doi: 10.1016/j.chemosphere.2015.12.063. Epub 2015 Dec 30.

Abstract

Municipal solid waste incinerator bottom ash (MSWIBA) has long been regarded as an alternative building material in the construction industry. However, the pollutants contained in the bottom ash could potentially leach out and contaminate the local environment, which presents an obstacle to the reuse of the materials. To evaluate the environmental feasibility of using MSWIBA as a recycled material in construction, the leaching derived ecotoxicity was assessed. The leaching behavior of MSWIBA under various conditions, including the extractant type, leaching time, liquid-to-solid (L/S) ratio, and leachate pH were investigated, and the phytotoxicity of these leachates on wheat (Triticum aestivum L.) seed germination was determined. Moreover, the correlation between the germination index and the concentrations of various chemical constituents in the MSWIBA leachates was assessed using multivariate statistics with principal component analysis and Pearson's correlation analysis. It was found that, heavy metal concentrations in the leachate were pH and L/S ratio dependent, but were less affected by leaching time. Heavy metals were the main pollutants present in wheat seeds. Heavy metals (especially Ba, Cr, Cu and Pb) had a substantial inhibitory effect on wheat seed germination and root elongation. To safely use MSWIBA in construction, the potential risk and ecotoxicity of leached materials must be addressed.

摘要

城市固体废弃物焚烧炉底灰(MSWIBA)长期以来一直被视为建筑行业的一种替代建筑材料。然而,底灰中所含的污染物可能会渗出并污染当地环境,这对材料的再利用构成了障碍。为了评估在建筑中使用MSWIBA作为再生材料的环境可行性,对浸出产生的生态毒性进行了评估。研究了MSWIBA在各种条件下的浸出行为,包括萃取剂类型、浸出时间、液固比(L/S)和浸出液pH值,并测定了这些浸出液对小麦(Triticum aestivum L.)种子萌发的植物毒性。此外,使用主成分分析和Pearson相关分析的多元统计方法评估了发芽指数与MSWIBA浸出液中各种化学成分浓度之间的相关性。结果发现,浸出液中的重金属浓度取决于pH值和液固比,但受浸出时间的影响较小。重金属是小麦种子中的主要污染物。重金属(尤其是Ba、Cr、Cu和Pb)对小麦种子萌发和根伸长有显著的抑制作用。为了在建筑中安全使用MSWIBA,必须解决浸出材料的潜在风险和生态毒性问题。

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