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低温制备具有增强可见光光催化活性的棕色二氧化钛。

Low-temperature fabrication of brown TiO2 with enhanced photocatalytic activities under visible light.

作者信息

Wang Mingzheng, Nie Biao, Yee Ka-Kit, Bian Haidong, Lee Chris, Lee Hung Kay, Zheng Bo, Lu Jian, Luo Linbao, Li Yang Yang

机构信息

School of Electronic Science and Applied Physics, Hefei University of Technology, Hefei, Anhui 230009, China and Center Of Super-Diamond and Advanced Films (COSDAF), Centre for Functional Photonics, and Department of Physics and Materials Science, City University of Hong Kong, Kowloon, Hong Kong, China.

Center Of Super-Diamond and Advanced Films (COSDAF), Centre for Functional Photonics, and Department of Physics and Materials Science, City University of Hong Kong, Kowloon, Hong Kong, China.

出版信息

Chem Commun (Camb). 2016 Feb 18;52(14):2988-91. doi: 10.1039/c5cc09176d.

Abstract

Here we report a facile one-step low-temperature solution-based method to treat native TiO2 with NaH. The NaH treatment effectively induces the Ti(iii) species and oxygen vacancies into the TiO2 host lattice, and enables the absorption edge of TiO2 to be conveniently adjusted from the UV region to the red end of the visible spectrum.

摘要

在此,我们报道了一种简便的基于低温溶液的一步法,用于用NaH处理天然TiO₂。NaH处理有效地将Ti(iii)物种和氧空位引入TiO₂主体晶格,并使TiO₂的吸收边缘能够方便地从紫外区域调整到可见光谱的红色端。

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