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在稳健的铯铅卤化物钙钛矿纳米线中产生激光。

Lasing in robust cesium lead halide perovskite nanowires.

作者信息

Eaton Samuel W, Lai Minliang, Gibson Natalie A, Wong Andrew B, Dou Letian, Ma Jie, Wang Lin-Wang, Leone Stephen R, Yang Peidong

机构信息

Department of Chemistry, University of California, Berkeley, CA 94720;

Department of Chemistry, University of California, Berkeley, CA 94720; Chemical Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, CA 94720;

出版信息

Proc Natl Acad Sci U S A. 2016 Feb 23;113(8):1993-8. doi: 10.1073/pnas.1600789113. Epub 2016 Feb 9.

Abstract

The rapidly growing field of nanoscale lasers can be advanced through the discovery of new, tunable light sources. The emission wavelength tunability demonstrated in perovskite materials is an attractive property for nanoscale lasers. Whereas organic-inorganic lead halide perovskite materials are known for their instability, cesium lead halides offer a robust alternative without sacrificing emission tunability or ease of synthesis. Here, we report the low-temperature, solution-phase growth of cesium lead halide nanowires exhibiting low-threshold lasing and high stability. The as-grown nanowires are single crystalline with well-formed facets, and act as high-quality laser cavities. The nanowires display excellent stability while stored and handled under ambient conditions over the course of weeks. Upon optical excitation, Fabry-Pérot lasing occurs in CsPbBr3 nanowires with an onset of 5 μJ cm(-2) with the nanowire cavity displaying a maximum quality factor of 1,009 ± 5. Lasing under constant, pulsed excitation can be maintained for over 1 h, the equivalent of 10(9) excitation cycles, and lasing persists upon exposure to ambient atmosphere. Wavelength tunability in the green and blue regions of the spectrum in conjunction with excellent stability makes these nanowire lasers attractive for device fabrication.

摘要

通过发现新型可调谐光源,可以推动快速发展的纳米级激光器领域。钙钛矿材料中所展示的发射波长可调性对于纳米级激光器来说是一种极具吸引力的特性。尽管有机 - 无机卤化铅钙钛矿材料以其不稳定性而闻名,但铯铅卤化物提供了一种稳健的替代方案,同时不牺牲发射可调性或合成的简便性。在此,我们报告了铯铅卤化物纳米线的低温溶液相生长,其表现出低阈值激光发射和高稳定性。生长的纳米线为单晶,具有良好的晶面,并且充当高质量的激光腔。在数周的时间里,这些纳米线在环境条件下储存和处理时显示出优异的稳定性。在光激发下,CsPbBr3纳米线中出现法布里 - 珀罗激光发射,起始能量为5 μJ cm(-2),纳米线腔的最大品质因数为1,009 ± 5。在恒定脉冲激发下的激光发射可以维持超过1小时,相当于10(9)次激发循环,并且在暴露于环境大气时激光发射仍然持续。光谱中绿色和蓝色区域的波长可调性以及出色的稳定性使得这些纳米线激光器对于器件制造具有吸引力。

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Proc Natl Acad Sci U S A. 2016 Feb 23;113(8):1993-8. doi: 10.1073/pnas.1600789113. Epub 2016 Feb 9.

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