具有不同长度间隔基团的盘状-立方二元体的合成与自组装。
The synthesis and self-assembly of disc-cube dyads with spacers of different lengths.
作者信息
Zhang Meng-Yao, Gu Ke-Hua, Zhou Yu, Zhou Sheng, Fan Xing-He, Shen Zhihao
机构信息
Beijing National Laboratory for Molecular Sciences, Key Laboratory of Polymer Chemistry and Physics of Ministry Education, Center for Soft Matter Science and Engineering, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China.
出版信息
Chem Commun (Camb). 2016 Mar 11;52(20):3923-6. doi: 10.1039/c5cc10620f. Epub 2016 Feb 12.
Disc-cube dyads with a polyhedral oligomeric silsesquioxane (POSS) molecule covalently attached to a hexa-peri-hexabenzocoronene (HBC) molecule were designed and synthesized. The results demonstrate that the length of a spacer plays an important role in the self-assembly behavior of the HBC-POSS dyad.
设计并合成了一种将多面体低聚倍半硅氧烷（POSS）分子共价连接到六并六苯并蔻（HBC）分子上的盘-立方体二元体。结果表明，间隔基的长度在HBC-POSS二元体的自组装行为中起着重要作用。
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