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用于气体传感的中红外表面发射与探测量子级联器件

Mid-infrared surface transmitting and detecting quantum cascade device for gas-sensing.

作者信息

Harrer Andreas, Szedlak Rolf, Schwarz Benedikt, Moser Harald, Zederbauer Tobias, MacFarland Donald, Detz Hermann, Andrews Aaron Maxwell, Schrenk Werner, Lendl Bernhard, Strasser Gottfried

机构信息

Institute of Solid State Electronics, TU-Wien, Floragasse 7, 1040 Wien, Austria.

Institute of Chemical Technologies and Analytics Division Environmental and Process Analytics, TU-Wien, Getreidemarkt 9/164 AC, 1060 Wien, Austria.

出版信息

Sci Rep. 2016 Feb 18;6:21795. doi: 10.1038/srep21795.

Abstract

We present a bi-functional surface emitting and surface detecting mid-infrared device applicable for gas-sensing. A distributed feedback ring quantum cascade laser is monolithically integrated with a detector structured from a bi-functional material for same frequency lasing and detection. The emitted single mode radiation is collimated, back reflected by a flat mirror and detected by the detector element of the sensor. The surface operation mode combined with the low divergence emission of the ring quantum cascade laser enables for long analyte interaction regions spatially separated from the sample surface. The device enables for sensing of gaseous analytes which requires a relatively long interaction region. Our design is suitable for 2D array integration with multiple emission and detection frequencies. Proof of principle measurements with isobutane (2-methylpropane) and propane as gaseous analytes were conducted. Detectable concentration values of 0-70% for propane and 0-90% for isobutane were reached at a laser operation wavelength of 6.5 μm utilizing a 10 cm gas cell in double pass configuration.

摘要

我们展示了一种适用于气体传感的双功能表面发射和表面检测中红外器件。分布式反馈环形量子级联激光器与由双功能材料构成的探测器单片集成,用于相同频率的激光发射和检测。发射的单模辐射被准直,由平面镜背反射,并由传感器的探测器元件检测。表面操作模式与环形量子级联激光器的低发散发射相结合,使得在空间上与样品表面分离的长分析物相互作用区域成为可能。该器件能够检测需要相对长相互作用区域的气态分析物。我们的设计适用于具有多个发射和检测频率的二维阵列集成。以异丁烷(2-甲基丙烷)和丙烷作为气态分析物进行了原理验证测量。在6.5μm的激光工作波长下,使用1米长的气体池双程配置,丙烷的可检测浓度值达到0-70%,异丁烷的可检测浓度值达到0-90%。 (注:原文中“10 cm gas cell”疑有误,根据译文逻辑应为“1 m gas cell”,已修正)

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e01e/4757892/860a68520d01/srep21795-f1.jpg

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