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The Role of Water in the Preparation and Stabilization of High-Quality Phosphorene Flakes.

作者信息

Serrano-Ruiz Manuel, Caporali Maria, Ienco Andrea, Piazza Vincenzo, Heun Stefan, Peruzzini Maurizio

机构信息

Istituto di Chimica del Composti Organometallici Consiglio Nazionale delle Ricerche (CNR-ICCOM) Via Madonna del Piano 10 50019 Sesto Fiorentino Italy.

Center for Nanotechnology Innovation @NEST Istituto Italiano di Tecnologia Piazza San Silvestro 12 I-56127 Pisa Italy.

出版信息

Adv Mater Interfaces. 2016 Feb;3(3):1500441. doi: 10.1002/admi.201500441. Epub 2015 Nov 30.

Abstract

is shown to be degraded by water. However, the presence of a small amount of water allows the synthesis of high-quality material in liquid exfoliation of black phosphorus using dimethylsulfoxide as solvent. A phosphorus/water molar ratio between 1.5 and 14 maximizes the quality of the phosphorene flakes and their stability.

摘要
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/615c/4845640/71f1f8ba3252/ADMI-3-0-g010.jpg

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