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中试规模下使用聚酰胺纳滤膜进行饮用水处理过程中的水回收

Water reclamation during drinking water treatments using polyamide nanofiltration membranes on a pilot scale.

作者信息

Kukučka Miroslav, Kukučka Nikoleta, Habuda-Stanić Mirna

机构信息

EnviroTech d.o.o, Sterije Popovića 42, 23300, Kikinda, Serbia.

Faculty of Food Technology Osijek, Josip Juraj Strossmayer University of Osijek, Franje Kuhača 20, 31000, Osijek, Croatia.

出版信息

Environ Sci Pollut Res Int. 2016 Sep;23(18):17919-27. doi: 10.1007/s11356-016-6919-3. Epub 2016 Jun 2.

Abstract

The aim of this study was to investigate the performances of polyamide nanofiltration membranes during water reclamation. The study was conducted using nanofiltration concentrates obtained from two different nanofiltration drinking water treatment plants placed in the northern part of Serbia (Kikinda and Zrenjanin). Used nanofiltration concentrates contained high concentrations of arsenic (45 and 451 μg/L) and natural organic matter (43.1 and 224.40 mgKMnO4/L). Performances of polyamide nanofiltration membranes during water reclamation were investigated under various fluxes and transmembrane pressures in order to obtain drinking water from nanofiltration concentrates and, therefore, reduce the amount of produced concentrates and minimize the waste that has to be discharged in the environment. Applied polyamide nanofiltration membranes showed better removal efficiency during water reclamation when the concentrate with higher content of arsenic and natural organic matter was used while the obtained permeates were in accordance with European regulations. This study showed that total concentrate yield can be reduced to ~5 % of the optimum flux value, in both experiments. The obtained result for concentrate yield under the optimum flux presents considerable amount of reclaimed drinking water and valuable reduced quantity of produced wastewater.

摘要

本研究的目的是调查聚酰胺纳滤膜在水回收过程中的性能。该研究使用从塞尔维亚北部的两个不同的纳滤饮用水处理厂(基金达和兹雷尼亚宁)获得的纳滤浓缩液进行。使用的纳滤浓缩液含有高浓度的砷(45和451μg/L)和天然有机物(43.1和224.40mgKMnO4/L)。为了从纳滤浓缩液中获得饮用水,从而减少产生的浓缩液量并尽量减少必须排放到环境中的废物,在各种通量和跨膜压力下研究了聚酰胺纳滤膜在水回收过程中的性能。当使用砷和天然有机物含量较高的浓缩液时,应用的聚酰胺纳滤膜在水回收过程中表现出更好的去除效率,而获得的渗透液符合欧洲法规。本研究表明,在两个实验中,总浓缩液产率均可降低至最佳通量值的约5%。在最佳通量下获得的浓缩液产率结果表明有大量的回收饮用水以及显著减少的产生废水量。

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