一种高度稳定的非滞后性{铜（tebpz）金属有机框架+水}分子弹簧。
A Highly Stable Nonhysteretic {Cu (tebpz) MOF+water} Molecular Spring.
作者信息
Grosu Yaroslav, Li Mian, Peng Yun-Lei, Luo Dong, Li Dan, Faik Abdessamad, Nedelec Jean-Marie, Grolier Jean-Pierre
机构信息
Institut de Chimie de Clermont-Ferrand, Universite Clermont Auvergne, SIGMA Clermont, BP 10448, 63000, Clermont-Ferrand, France.
UMR 6296, CNRS, 63177, Aubiere, France.
出版信息
Chemphyschem. 2016 Nov 4;17(21):3359-3364. doi: 10.1002/cphc.201600567. Epub 2016 Sep 9.
A molecular spring formed by a hydrophobic metal-organic framework Cu (tebpz) (tebpz=3,3',5,5'-tetraethyl-4,4'-bipyrazolate) and water is presented. This nanoporous heterogeneous lyophobic system (HLS) has exceptional properties compared to numerous reported systems of such type in terms of stability, efficiency, and operating pressure. Mechanical and thermal energetic characteristics as well as stability of the system are discussed and compared in detail with those of other previously reported HLS.
本文介绍了一种由疏水性金属有机框架Cu(tebpz)(tebpz = 3,3',5,5'-四乙基-4,4'-联吡唑)和水形成的分子弹簧。与众多已报道的此类纳米多孔非均相疏液体系(HLS)相比，该体系在稳定性、效率和操作压力方面具有优异的性能。详细讨论并比较了该体系的机械和热能量特性以及稳定性与其他先前报道的HLS的相关特性。
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