Key Laboratory for Green Technology of Ministry of Education, School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China.
Department of Chemical and Environmental Engineering, Yale University, New Haven, Connecticut 06520-8286, USA.
Chem Soc Rev. 2016 Oct 24;45(21):5888-5924. doi: 10.1039/c5cs00579e.
One of the greatest challenges to the sustainability of modern society is an inadequate supply of clean water. Due to its energy-saving and cost-effective features, membrane technology has become an indispensable platform technology for water purification, including seawater and brackish water desalination as well as municipal or industrial wastewater treatment. However, membrane fouling, which arises from the nonspecific interaction between membrane surface and foulants, significantly impedes the efficient application of membrane technology. Preparing antifouling membranes is a fundamental strategy to deal with pervasive fouling problems from a variety of foulants. In recent years, major advancements have been made in membrane preparation techniques and in elucidating the antifouling mechanisms of membrane processes, including ultrafiltration, nanofiltration, reverse osmosis and forward osmosis. This review will first introduce the major foulants and the principal mechanisms of membrane fouling, and then highlight the development, current status and future prospects of antifouling membranes, including antifouling strategies, preparation techniques and practical applications. In particular, the strategies and mechanisms for antifouling membranes, including passive fouling resistance and fouling release, active off-surface and on-surface strategies, will be proposed and discussed extensively.
现代社会可持续发展面临的最大挑战之一是清洁水的供应不足。由于其节能和经济高效的特点,膜技术已成为水净化的不可或缺的平台技术,包括海水和苦咸水淡化以及城市或工业废水处理。然而,膜污染是由膜表面和污染物之间的非特异性相互作用引起的,这极大地阻碍了膜技术的有效应用。制备抗污染膜是应对各种污染物普遍存在的污染问题的根本策略。近年来,在膜制备技术和膜过程的抗污染机制方面取得了重大进展,包括超滤、纳滤、反渗透和正向渗透。本文首先介绍了主要的污染物和膜污染的主要机制,然后重点介绍了抗污染膜的发展、现状和未来前景,包括抗污染策略、制备技术和实际应用。特别是,将广泛提出和讨论抗污染膜的策略和机制,包括被动抗污染阻力和污染释放、表面外和表面上的主动策略。