Crystal structure of hexa-kis-(dimethyl sulfoxide-κO)manganese(II) diiodide.
作者信息
Glatz Mathias, Schroffenegger Martina, Weil Matthias, Kirchner Karl
机构信息
Institute of Applied Synthetic Chemistry, Vienna University of Technology, Getreidemarkt 9/163, A-1060 Vienna, Austria.
Institute for Chemical Technologies and Analytics, Division of Structural Chemistry, Vienna University of Technology, Getreidemarkt 9/164-SC, A-1060 Vienna, Austria.
出版信息
Acta Crystallogr E Crystallogr Commun. 2016 Jun 10;72(Pt 7):904-6. doi: 10.1107/S2056989016008896. eCollection 2016 Jul 1.
The asymmetric unit of the title salt, [Mn(C2H6OS)6]I2, consists of one Mn(II) ion, six O-bound dimethyl sulfoxide (DMSO) ligands and two I(-) counter-anions. The isolated complex cations have an octa-hedral configuration and are grouped in hexa-gonally arranged rows extending parallel to [100]. The two I(-) anions are located between the rows and are linked to the cations through two weak C-H⋯I inter-actions.
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