钯环催化：铃木-宫浦交叉偶联反应的一项创新。
Palladacycle catalysis: an innovation to the Suzuki-Miyaura cross-coupling reaction.
作者信息
Lucio-Martínez Fátima, Adrio Luis A, Polo-Ces Paula, Ortigueira Juan M, Fernández Jesús J, Adams Harry, Pereira M Teresa, Vila José M
机构信息
Departamento de Química Inorgánica, Universidade de Santiago de Compostela, Avenida das Ciencias s/n, 15782 Santiago de Compostela, Spain.
出版信息
Dalton Trans. 2016 Nov 28;45(44):17598-17601. doi: 10.1039/c6dt03542f. Epub 2016 Oct 24.
PMID:27774544
Abstract
Herein we report a Suzuki-Miyaura type cross-coupling between an aryl halide and a functionalized boronic acid palladacycle in the absence of an external catalyst. This reaction is an unprecedented case of catalysis in palladium metallacycle chemistry.
摘要
在此，我们报道了在没有外部催化剂的情况下，芳基卤化物与功能化硼酸钯环之间的铃木-宫浦型交叉偶联反应。该反应是钯金属环化学中前所未有的催化实例。
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