钌（II）双羧酸盐催化的C(sp²)-H和C(sp³)-H键硼化反应
Ruthenium(II) Biscarboxylate-Catalyzed Borylations of C(sp )-H and C(sp )-H Bonds.
作者信息
Sarkar Suman De, Kumar N Y Phani, Ackermann Lutz
机构信息
Institut für Organische und Biomolekulare Chemie, Georg-August-Universität Göttingen, Tammannstrasse 2, 37077, Göttingen, Germany.
出版信息
Chemistry. 2017 Jan 1;23(1):84-87. doi: 10.1002/chem.201604943. Epub 2016 Nov 11.
PMID:27779339
Abstract
Versatile borylations of C(sp )-H and C(sp )-H were achieved with ruthenium(II) biscarboxylate complexes. The robust nature of the ruthenium(II) catalyst enabled C(sp )-H borylation on pyrrolidines, piperidines, and azepanes with ample scope and excellent positional selectivity control.
摘要
利用二羧酸钌（II）配合物实现了C(sp³)-H和C(sp²)-H的多功能硼化反应。钌（II）催化剂的稳定性使得在吡咯烷、哌啶和氮杂环庚烷上进行C(sp³)-H硼化反应具有广泛的范围和出色的位置选择性控制。
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