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原位静电纺丝制备壳聚糖纳米结构用于高效 PM2.5 捕获。

Chitosan nanostructures by in situ electrospinning for high-efficiency PM2.5 capture.

机构信息

Collaborative Innovation Center for Nanomaterials & Devices, College of Physics, Qingdao University, Qingdao 266071, China.

出版信息

Nanoscale. 2017 Mar 23;9(12):4154-4161. doi: 10.1039/c6nr09525a.

Abstract

Nanofiber-based air filters and electrostatic precipitation have stimulated considerable interest because of their high-efficiency for PM2.5 capture. In this paper, we introduce a new method of in situ electrospinning (e-spinning) of nanostructures into a polluted enclosed space to efficiently clean the air. From the comparisons of different polymer precursors and different PM2.5 capture techniques, it can be seen that in situ e-spinning of chitosan aqueous solution into the air exhibits the best PM2.5 capture efficiency, which may be attributed to the stronger polarity of chitosan and the synergistic effect of the strong electrostatic adsorption and surface adhesion of the electrospun (e-spun) nanofibers. A removal rate as high as 3.7 μg m s was obtained using this technology with a high efficiency of more than 95% PM2.5 capture. The results obtained from a field test in a smoking room (∼5 × 6 × 3 m) are still in great agreement with those obtained in an experimental box (∼25 × 30 × 35 cm). More importantly, chitosan is non-toxic and biodegradable, and is harmless to human health when used as a precursor for in situ e-spinning for PM2.5 capture.

摘要

基于纳米纤维的空气过滤器和静电沉淀由于其对 PM2.5 捕获的高效率而引起了相当大的兴趣。在本文中,我们介绍了一种将纳米结构原位电纺(e-纺丝)到污染封闭空间中的新方法,以有效地清洁空气。通过比较不同的聚合物前体和不同的 PM2.5 捕获技术,可以看出将壳聚糖水溶液原位电纺到空气中表现出最佳的 PM2.5 捕获效率,这可能归因于壳聚糖的更强极性和电纺纳米纤维的强静电吸附和表面附着力的协同效应。使用这项技术可以获得高达 3.7μg m s 的去除率,PM2.5 捕获效率超过 95%。在吸烟室(约 5×6×3 m)中进行的现场测试结果与在实验箱(约 25×30×35 cm)中获得的结果仍然非常吻合。更重要的是,壳聚糖是无毒和可生物降解的,并且在用作 PM2.5 捕获的原位电纺前体时对人体健康无害。

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