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嗜酸氧化亚铁硫杆菌对磷二次原料的增值利用

Valorization of Phosphorus Secondary Raw Materials by Acidithiobacillus ferrooxidans.

作者信息

Wyciszkiewicz Małgorzata, Saeid Agnieszka, Malinowski Przemysław, Chojnacka Katarzyna

机构信息

Department of Advanced Material Technologies, Faculty of Chemistry, Wroclaw University of Technology, Smoluchowskiego 25, 50-372 Wroclaw, Poland.

Basic Science Center, University of Applied Sciences in Nysa, Armii Krajowej 7, 48-300 Nysa, Poland.

出版信息

Molecules. 2017 Mar 16;22(3):473. doi: 10.3390/molecules22030473.

Abstract

This paper presents the possibility of producing phosphorus fertilizers through utilization in secondary raw materials solubilization. Phosphorus was obtained from the bones of poultry and fish as well as from Morocco phosphorite. Four doses of poultry bones and fish bones were used in the experiment (2, 4, 10 and 20 g/L) and two doses (2 and 4 g/L) of phosphorite were also used. The experimenters measured the final pH, which increased in proportion to the increase in the number of poultry bone doses, whereas in the case of fish bones it decreased in proportion to the increase in the number of fish bone doses. Only in the case of phosphorite, where 10 g/L were used, there was a slight increase in pH during solubilization observed. The highest phosphorus concentration of 1.9% (expressed as P₂O₅) was found for the solubilization performed on fish bones with the highest dose (20 g/L). The formulation obtained in this study meets the necessary requirements for use as a bio-fertilizer because of the relatively low content of P₂O₅ and the low content of toxic elements. The results confirm the utilization of in the biosolubilization of phosphorus renewable raw materials that can alleviate the problem of the world's depleting phosphorite deposits.

摘要

本文介绍了通过利用二次原料溶解来生产磷肥的可能性。磷取自家禽和鱼类的骨头以及摩洛哥磷矿。实验中使用了四剂家禽骨头和鱼骨(2、4、10和20克/升),还使用了两剂(2和4克/升)磷矿。实验者测量了最终pH值,其随家禽骨剂量的增加而升高,而对于鱼骨,其随鱼骨剂量的增加而降低。仅在使用10克/升磷矿的情况下,溶解过程中观察到pH值略有升高。在使用最高剂量(20克/升)鱼骨进行的溶解中,发现最高磷浓度为1.9%(以P₂O₅表示)。由于P₂O₅含量相对较低且有毒元素含量低,本研究中获得的配方满足用作生物肥料的必要要求。结果证实了可再生原料磷的生物溶解中的利用,这可以缓解世界磷矿储量枯竭的问题。

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