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源自生化和化学途径的丁醇:综述

-Butanol derived from biochemical and chemical routes: A review.

作者信息

Ndaba B, Chiyanzu I, Marx S

机构信息

Focus area: Energy system, School of Chemical and Minerals Engineering, North-West University (Potchefstroom Campus), Potchefstroom, South Africa.

出版信息

Biotechnol Rep (Amst). 2015 Aug 5;8:1-9. doi: 10.1016/j.btre.2015.08.001. eCollection 2015 Dec.

Abstract

Traditionally, bio-butanol is produced with the ABE (Acetone Butanol Ethanol) process using species to ferment sugars from biomass. However, the route is associated with some disadvantages such as low butanol yield and by-product formation (acetone and ethanol). On the other hand, butanol can be directly produced from ethanol through aldol condensation over metal oxides/ hydroxyapatite catalysts. This paper suggests that the chemical conversion route is more preferable than the ABE process, because the reaction proceeds more quickly compared to the fermentation route and fewer steps are required to get to the product.

摘要

传统上,生物丁醇是通过ABE(丙酮-丁醇-乙醇)工艺,利用特定菌种将生物质中的糖类发酵生产出来的。然而,该工艺存在一些缺点,如丁醇产量低以及会形成副产物(丙酮和乙醇)。另一方面,丁醇可以通过乙醇在金属氧化物/羟基磷灰石催化剂上进行羟醛缩合反应直接制得。本文认为,与ABE工艺相比,化学转化路线更具优势,因为与发酵路线相比,该反应进行得更快,且生产产物所需步骤更少。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/85a3/4980751/8533eada25e2/gr2.jpg

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