Morais Alysson F, Silva Ivan G N, Sree Sreeprasanth P, de Melo Fernando M, Brabants Gert, Brito Hermi F, Martens Johan A, Toma Henrique E, Kirschhock Christine E A, Breynaert Eric, Mustafa Danilo
Instituto de Física da Universidade de São Paulo, 05508-090 - São Paulo, SP, Brazil.
Chem Commun (Camb). 2017 Jun 29;53(53):7341-7344. doi: 10.1039/c7cc02097j.
Self-supported oligo-layered ZnAlEu LDH nanotubes (∅ 20 nm) self-assemble upon controlled hydrolysis of the metal ions (Zn, Al, Eu) in the presence of 1,3,5-benzenetricarboxylate anions and non-ionic worm-like micelles. Their high surface area and easily accessible cylindrical mesopores (175 m g; 0.75 cm g) facilitate interaction with 5 nm CdTe quantum dots, enhancing the overall luminescence behavior.
自支撑的寡层ZnAlEu层状双氢氧化物纳米管(直径20纳米)在1,3,5-苯三甲酸根阴离子和非离子蠕虫状胶束存在的情况下,通过金属离子(锌、铝、铕)的控制水解自组装而成。它们的高表面积和易于接近的圆柱形中孔(175平方米/克;0.75立方厘米/克)有助于与5纳米的碲化镉量子点相互作用,增强整体发光行为。