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通过绿色合成法用铜纳米颗粒浸渍的巴巴苏椰子活性炭用于去除水溶液中的硝酸盐。

Activated carbon of Babassu coconut impregnated with copper nanoparticles by green synthesis for the removal of nitrate in aqueous solution.

作者信息

Paixão Rebecca Manesco, Reck Isabela Maria, Bergamasco Rosângela, Vieira Marcelo Fernandes, Vieira Angélica Marquetotti Salcedo

机构信息

a Chemical Engineering Department , State University of Maringa , Maringa , Brazil.

b Postgraduate Program in Food Science , State University of Maringa , Maringa , Brazil.

出版信息

Environ Technol. 2018 Aug;39(15):1994-2003. doi: 10.1080/09593330.2017.1345990. Epub 2017 Jul 4.

Abstract

The present study was conducted to impregnate the surface of a carbon of vegetable origin with copper nanoparticles by the green synthesis method with the aqueous extract of Hibiscus sabdariffa flowers, rich in phenolic compounds, which are responsible for the reduction and impregnation of metal nanoparticles. Batch adsorption assays were conducted aimed at nitrate removal with pure (GAC) and impregnated (IGAC) carbon, for comparative purposes. It was found that impregnation increases the efficiency of the carbon by four times in terms of the maximum adsorption capacity, which was 10.13 mg g at 45°C for GAC and 45.01 mg g at 15°C for IGAC, indicating that this is a promising material for the removal of nitrate in waters with an excess of this ion.

摘要

本研究旨在通过绿色合成法,用富含酚类化合物的玫瑰茄花水提取物将植物源碳的表面浸渍铜纳米颗粒,这些酚类化合物负责金属纳米颗粒的还原和浸渍。为了进行比较,采用纯(GAC)和浸渍(IGAC)碳进行了批量吸附试验以去除硝酸盐。结果发现,就最大吸附容量而言,浸渍使碳的效率提高了四倍,45℃时GAC的最大吸附容量为10.13 mg/g,15℃时IGAC的最大吸附容量为45.01 mg/g,这表明该材料对于去除水中过量的这种离子是一种有前景的材料。

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