Zhang Shiguo, Dokko Kaoru, Watanabe Masayoshi
Department of Chemistry and Biotechnology , Yokohama National University , 79-5 Tokiwadai , Hodogaya-ku , Yokohama 240-8501 , Japan . Email:
Chem Sci. 2015 Jul 15;6(7):3684-3691. doi: 10.1039/c5sc01374g. Epub 2015 May 27.
Solidification of fluidic ionic liquids into porous materials yields porous ionic networks that combine the unique characteristics of ionic liquids with the common features of polymers and porous materials. This minireview reports the most recent advances in the design of porous ionic liquids. A summary of the synthesis of ordered and disordered porous ionic liquid-based nanoparticles or membranes with or without templates is provided, together with the new concept of room temperature porous ionic liquids. As a versatile platform for functional materials, porous ionic liquids have shown widespread applications in catalysis, adsorption, sensing, actuation, This new research direction towards ionic liquids chemistry is still in its early stages but has great potential.
将流体离子液体固化为多孔材料可产生多孔离子网络,该网络将离子液体的独特特性与聚合物和多孔材料的共同特征结合在一起。本综述报道了多孔离子液体设计的最新进展。提供了有无模板的有序和无序多孔离子液体基纳米颗粒或膜合成的总结,以及室温多孔离子液体的新概念。作为功能材料的通用平台,多孔离子液体在催化、吸附、传感、驱动等方面已显示出广泛应用。离子液体化学这一新的研究方向仍处于早期阶段,但具有巨大潜力。