• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

(1 - x)BiNaTiO₃-xBaCaTiO₃无铅固溶体的压电陶瓷：准同型相界的化学位移，x = 0.06的案例研究

Piezoelectric Ceramics of the (1 - x)BiNaTiO₃-xBaCaTiO₃ Lead-Free Solid Solution: Chemical Shift of the Morphotropic Phase Boundary, a Case Study for x = 0.06.

作者信息

Vivar-Ocampo Rodrigo, Pardo Lorena, Ávila David, Morán Emilio, González Amador M, Bucio Lauro, Villafuerte-Castrejón María-Elena

机构信息

Instituto de Investigaciones en Materiales, Universidad Nacional Autónoma de México, Ciudad Universitaria, A.P. 70-360, México D.F. 04510, Mexico.

Instituto de Ciencia de Materiales de Madrid, CSIC, Sor Juana Inés de la Cruz, 3, Cantoblanco, 28049 Madrid, Spain.

出版信息

Materials (Basel). 2017 Jul 1;10(7):736. doi: 10.3390/ma10070736.

DOI:10.3390/ma10070736
PMID:28773096
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC5551779/
Abstract

Research and development of lead-free piezoelectric materials are still the hottest topics in the field of piezoelectricity. One of the most promising lead-free family of compounds to replace lead zirconate-titanate for actuators is that of BiNaTiO₃ (BNT) based solid solutions. The pseudo-binary (1 - )BiNaTiO₃-BaCaTiO₃ system has been proposed for high temperature capacitors and not yet fully explored as piezoelectric material. In this work, the solid solution with = 0.06 and = 0.10 was obtained by two different synthesis routes: solid state and Pechini, aiming at using reduced temperatures, both in synthesis (<800 °C) and sintering (<1150 °C), while maintaining appropriated piezoelectric performance. Crystal structure, ceramic grain size, and morphology depend on the synthesis route and were analyzed by X-ray diffraction, together with scanning and transmission electron microscopy. The effects of processing and ceramic microstructure on the structural, dielectric, ferroelectric, and piezoelectric properties were discussed in terms of a shift of the Morphotropic Phase Boundary, chemically induced by the synthesis route.

摘要

无铅压电材料的研发仍然是压电领域最热门的话题。用于致动器替代锆钛酸铅的最有前途的无铅化合物家族之一是基于BiNaTiO₃（BNT）的固溶体。伪二元（1 - ）BiNaTiO₃ - BaCaTiO₃体系已被提议用于高温电容器，但作为压电材料尚未得到充分探索。在这项工作中，通过两种不同的合成路线：固态法和佩琴尼法，获得了x = 0.06和y = 0.10的固溶体，旨在在合成（<800°C）和烧结（<1150°C）过程中使用较低温度，同时保持适当的压电性能。晶体结构、陶瓷晶粒尺寸和形态取决于合成路线，并通过X射线衍射以及扫描和透射电子显微镜进行了分析。从由合成路线化学诱导的准同型相界的移动角度讨论了加工和陶瓷微观结构对结构、介电、铁电和压电性能的影响。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3489/5551779/d29697a1cd47/materials-10-00736-g012.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3489/5551779/1e99e99572f8/materials-10-00736-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3489/5551779/0fdcd07216a0/materials-10-00736-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3489/5551779/426d6505e1d4/materials-10-00736-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3489/5551779/18cdbb3031fc/materials-10-00736-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3489/5551779/e0fc91b52520/materials-10-00736-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3489/5551779/991af077e0d6/materials-10-00736-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3489/5551779/70a90a40bd3c/materials-10-00736-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3489/5551779/966d0cf2abf7/materials-10-00736-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3489/5551779/e91f4592e7d4/materials-10-00736-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3489/5551779/9c7087618504/materials-10-00736-g010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3489/5551779/ad57b14f73d6/materials-10-00736-g011.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3489/5551779/d29697a1cd47/materials-10-00736-g012.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3489/5551779/1e99e99572f8/materials-10-00736-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3489/5551779/0fdcd07216a0/materials-10-00736-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3489/5551779/426d6505e1d4/materials-10-00736-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3489/5551779/18cdbb3031fc/materials-10-00736-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3489/5551779/e0fc91b52520/materials-10-00736-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3489/5551779/991af077e0d6/materials-10-00736-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3489/5551779/70a90a40bd3c/materials-10-00736-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3489/5551779/966d0cf2abf7/materials-10-00736-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3489/5551779/e91f4592e7d4/materials-10-00736-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3489/5551779/9c7087618504/materials-10-00736-g010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3489/5551779/ad57b14f73d6/materials-10-00736-g011.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3489/5551779/d29697a1cd47/materials-10-00736-g012.jpg

相似文献

1
Piezoelectric Ceramics of the (1 - x)BiNaTiO₃-xBaCaTiO₃ Lead-Free Solid Solution: Chemical Shift of the Morphotropic Phase Boundary, a Case Study for x = 0.06.(1 - x)BiNaTiO₃-xBaCaTiO₃无铅固溶体的压电陶瓷：准同型相界的化学位移，x = 0.06的案例研究
Materials (Basel). 2017 Jul 1;10(7):736. doi: 10.3390/ma10070736.
2
Comparative Study of Ferroelectric and Piezoelectric Properties of BNT-BKT-BT Ceramics near the Phase Transition Zone.相变区附近BNT-BKT-BT陶瓷铁电和压电性能的对比研究
Materials (Basel). 2018 Mar 1;11(3):361. doi: 10.3390/ma11030361.
3
Progress in engineering high strain lead-free piezoelectric ceramics.高应变无铅压电陶瓷的工程进展。
Sci Technol Adv Mater. 2010 Sep 10;11(4):044302. doi: 10.1088/1468-6996/11/4/044302. eCollection 2010 Aug.
4
Phase transition temperatures and piezoelectric properties of (Bi(1/2)Na(1/2))TiO3- and (Bi(1/2)K(1/2))TiO3-based bismuth perovskite lead-free ferroelectric ceramics.基于（Bi(1/2)Na(1/2))TiO3 和（Bi(1/2)K(1/2))TiO3 的铋钛矿型无铅铁电陶瓷的相变温度和压电性能
IEEE Trans Ultrason Ferroelectr Freq Control. 2009 Aug;56(8):1595-612. doi: 10.1109/TUFFC.2009.1224.
5
Microstructural and high-temperature dielectric, piezoelectric and complex impedance spectroscopic properties of KBiTiO modified NBT-BT lead-free ferroelectric ceramics.KBiTiO 改性的 NBT-BT 无铅铁电陶瓷的微观结构及高温介电、压电和复阻抗谱特性
Heliyon. 2023 Mar 23;9(4):e14761. doi: 10.1016/j.heliyon.2023.e14761. eCollection 2023 Apr.
6
Enhanced Ferroelectric and Dielectric Properties of Niobium-Doped Lead-Free Piezoceramics.铌掺杂无铅压电陶瓷的增强铁电和介电性能
Materials (Basel). 2023 Jan 4;16(2):477. doi: 10.3390/ma16020477.
7
A molecular perovskite solid solution with piezoelectricity stronger than lead zirconate titanate.一种分子钙钛矿固溶体，其压电性强于锆钛酸铅。
Science. 2019 Mar 15;363(6432):1206-1210. doi: 10.1126/science.aav3057.
8
Fabrication of Lead-Free BiNaTiO₃ Thin Films by Aqueous Chemical Solution Deposition.通过水热化学溶液沉积法制备无铅BiNaTiO₃薄膜。
Materials (Basel). 2017 Feb 22;10(2):213. doi: 10.3390/ma10020213.
9
(Na, K)NbO3-Based Ceramics for Self-Powered Energy Harvesting Applications.用于自供电能量收集应用的（钠，钾）铌酸盐基陶瓷
J Nanosci Nanotechnol. 2015 Mar;15(3):2360-3. doi: 10.1166/jnn.2015.10268.
10
Electric-Field-Induced Phase Transformation and Frequency-Dependent Behavior of Bismuth Sodium Titanate-Barium Titanate.电场诱导钛酸铋钠-钛酸钡的相变及频率相关行为
Materials (Basel). 2020 Feb 27;13(5):1054. doi: 10.3390/ma13051054.

本文引用的文献

1
Towards Lead-Free Piezoceramics: Facing a Synthesis Challenge.迈向无铅压电陶瓷：面临合成挑战。
Materials (Basel). 2016 Jan 2;9(1):21. doi: 10.3390/ma9010021.
2
Ferroelectrics under the Synchrotron Light: A Review.同步辐射光下的铁电体：综述
Materials (Basel). 2015 Dec 30;9(1):14. doi: 10.3390/ma9010014.
3
Superior Piezoelectric Properties in Potassium-Sodium Niobate Lead-Free Ceramics.钾钠铌酸钾无铅陶瓷的优异压电性能。
Adv Mater. 2016 Oct;28(38):8519-8523. doi: 10.1002/adma.201601859. Epub 2016 Jul 21.
4
Creation and destruction of morphotropic phase boundaries through electrical poling: a case study of lead-free (Bi(1/2)Na(1/2))TiO3-BaTiO3 piezoelectrics.通过电极化创建和破坏弛豫铁电体中的准同型相界：无铅（Bi(1/2)Na(1/2))TiO3-BaTiO3 铁电体的案例研究。
Phys Rev Lett. 2012 Sep 7;109(10):107602. doi: 10.1103/PhysRevLett.109.107602.
5
Field-induced phase transition and relaxor character in submicrometer-structured lead-free (Bi0.5Na0.5)0.94Ba0.06TiO3 piezoceramics at the morphotropic phase boundary.在准同型相界处亚微米结构的无铅（Bi0.5Na0.5）0.94Ba0.06TiO3 压电陶瓷中的场诱导相转变和弛豫特性。
IEEE Trans Ultrason Ferroelectr Freq Control. 2011 Sep;58(9):1893-904. doi: 10.1109/TUFFC.2011.2029.
6
Large piezoelectric effect in Pb-free ceramics.无铅陶瓷中的大压电效应。
Phys Rev Lett. 2009 Dec 18;103(25):257602. doi: 10.1103/PhysRevLett.103.257602. Epub 2009 Dec 15.
7
Phase transition temperatures and piezoelectric properties of (Bi(1/2)Na(1/2))TiO3- and (Bi(1/2)K(1/2))TiO3-based bismuth perovskite lead-free ferroelectric ceramics.基于（Bi(1/2)Na(1/2))TiO3 和（Bi(1/2)K(1/2))TiO3 的铋钛矿型无铅铁电陶瓷的相变温度和压电性能
IEEE Trans Ultrason Ferroelectr Freq Control. 2009 Aug;56(8):1595-612. doi: 10.1109/TUFFC.2009.1224.
8
Investigation of the structure and phase transitions in the novel A-site substituted distorted perovskite compound Na(0.5)Bi(0.5)TiO(3).新型A位取代畸变钙钛矿化合物Na(0.5)Bi(0.5)TiO(3)的结构与相变研究
Acta Crystallogr B. 2002 Apr;58(Pt 2):168-78. doi: 10.1107/s0108768101020845. Epub 2002 Mar 25.