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非生物因素对吡虫啉降解的影响

Effect of Abiotic Factors on Degradation of Imidacloprid.

作者信息

Mahapatra Bibhab, Adak Totan, Patil Naveen K B, Pandi G Guru P, Gowda G Basana, Yadav Manoj Kumar, Mohapatra S D, Rath P C, Munda Sushmita, Jena Mayabini

机构信息

Crop Protection Division, ICAR-National Rice Research Institute (Formerly Central Rice Research Institute), Cuttack, 753006, India.

Utkal University, Bhubaneswar, 751004, India.

出版信息

Bull Environ Contam Toxicol. 2017 Oct;99(4):475-480. doi: 10.1007/s00128-017-2159-6. Epub 2017 Aug 24.

Abstract

The role of soil moisture, light and pH on imidacloprid dissipation was investigated. A high performance liquid chromatography (HPLC) based method was developed to quantify imidacloprid present in soil with a recovery of more than 82%. Rate of dissipation of imidacloprid from soil was faster in submerged condition compared to field capacity and air dried condition. Imidacloprid dissipated non-significantly between sterile and non-sterile soils, but at field capacity, the dissipation was faster in non-sterile soil compared to sterile soil after 60 days of incubation. Similarly, under submergence, the dissipation of imidacloprid was 66.2% and 79.8% of the initial in sterile and non-sterile soils, respectively. Imidacloprid was rather stable in acidic and neutral water but was prone to photo-degradation. Therefore, imidacloprid degradation will be faster under direct sunlight and at higher soil moisture.

摘要

研究了土壤湿度、光照和pH值对吡虫啉消散的作用。开发了一种基于高效液相色谱(HPLC)的方法来定量土壤中存在的吡虫啉,回收率超过82%。与田间持水量和风干条件相比,淹水条件下吡虫啉从土壤中的消散速率更快。吡虫啉在无菌土壤和非无菌土壤之间的消散不显著,但在田间持水量条件下,培养60天后,非无菌土壤中的消散速度比无菌土壤快。同样,在淹水条件下,无菌土壤和非无菌土壤中吡虫啉的消散分别为初始量的66.2%和79.8%。吡虫啉在酸性和中性水中相当稳定,但易发生光降解。因此,在直射阳光下和较高土壤湿度下,吡虫啉的降解会更快。

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