Dailing Eric, Liu JianCheng, Lewis Steven, Stansbury Jeffery
Department of Chemical and Biological Engineering, University of Colorado, Boulder, CO 80309, USA.
Biomaterials Research Center, School of Dental Medicine, University of Colorado, Aurora, CO 80045, USA.
Macromol Symp. 2013 Jul;329(1):113-117. doi: 10.1002/masy.201200109. Epub 2013 Aug 23.
Reactive nanogels with diverse chemical and physical compositions were synthesized using solution free radical polymerization. Conventional monomer resins show a reduction in polymerization shrinkage and stress as well as improved bond strength when nanogels are used as a filler. Nanogels dispersed in inert solvent at appropriate concentrations form macroscopic networks with chemical compositions that are not directly available from the starting monomers.
采用溶液自由基聚合法合成了具有多种化学和物理组成的反应性纳米凝胶。当纳米凝胶用作填料时,传统单体树脂的聚合收缩率和应力降低,粘结强度提高。纳米凝胶以适当浓度分散在惰性溶剂中,形成具有从起始单体中无法直接获得的化学组成的宏观网络。