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碳纳米管的催化化学气相沉积合成:迈向高产率和低温生长

Catalytic CVD Synthesis of Carbon Nanotubes: Towards High Yield and Low Temperature Growth.

作者信息

Magrez Arnaud, Seo Jin Won, Smajda Rita, Mionić Marijana, Forró László

机构信息

Laboratory of Complex Mater Physics, Ecole Polytechnique Fédérale de Lausanne, 1015 Lausanne, Switzerland.

Center for Research on Electronically Advanced Materials, Ecole Polytechnique Fédérale de Lausanne, 1015 Lausanne, Switzerland.

出版信息

Materials (Basel). 2010 Nov 1;3(11):4871-4891. doi: 10.3390/ma3114871.

Abstract

The catalytic chemical vapor deposition (CCVD) is currently the most flexible and economically attractive method for the growth of carbon nanotubes. Although its principle is simple, the precisely controlled growth of carbon nanotubes remains very complex because many different parameters influence the growth process. In this article, we review our recent results obtained on the synthesis of carbon nanotubes via CCVD. We discuss the role of the catalyst and the catalyst support. Our recent results obtained from the water assisted growth and the equimolar C₂H₂-CO₂ reaction are also discussed. Both procedures lead to significantly enhanced carbon nanotube growth. In particular, the latter allows growing carbon nanotubes on diverse substrate materials at low temperatures.

摘要

催化化学气相沉积(CCVD)是目前用于生长碳纳米管最灵活且经济上最具吸引力的方法。尽管其原理简单,但由于许多不同参数会影响生长过程,碳纳米管的精确控制生长仍然非常复杂。在本文中,我们回顾了通过CCVD合成碳纳米管的近期成果。我们讨论了催化剂和催化剂载体的作用。还讨论了我们从水辅助生长和等摩尔C₂H₂ - CO₂反应中获得的近期结果。这两种方法都能显著提高碳纳米管的生长。特别是,后者能够在低温下在多种衬底材料上生长碳纳米管。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3400/5445774/185f2b8af041/materials-03-04871-g001.jpg

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