高浓度的对甲苯磺酸钠水溶液作为绿色介质用于烯烃氧化和亲核取代反应。
Concentrated Aqueous Sodium Tosylate as Green Medium for Alkene Oxidation and Nucleophilic Substitution Reactions.
机构信息
School of Chemistry, The Raymond and Beverly Sackler Faculty of Exact Sciences, Tel Aviv University , Tel Aviv 69978, Israel.
出版信息
J Org Chem. 2017 Nov 3;82(21):11609-11612. doi: 10.1021/acs.joc.7b01679.
PMID:28977752
Abstract
A hydrotropic solution of highly concentrated sodium tosylate (NaOTs) can be used as a recyclable medium for the environmentally benign oxidation of conjugated alkenes with HO. Both uncatalyzed and metal-catalyzed reactions provided the corresponding oxidation products in higher yields than in pure water or many common organic solvents.
摘要
高浓度对甲苯磺酸钠（NaOTs）的水溶媒可以作为一种可回收的介质，用于环境友好的共轭烯烃的 HO 氧化。未催化和金属催化的反应都比在纯水中或许多常见有机溶剂中提供了更高产率的相应氧化产物。
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