College of Chemistry, Sichuan University, Chengdu, 610064, China.
Sci Rep. 2017 Oct 6;7(1):12744. doi: 10.1038/s41598-017-12812-7.
Energetic salts/ionic liquids have received increasing attention as fascinating energetic materials, and the use of renewable compounds is a promising approach to developing energetic materials. Until recently, biomolecules have been used as raw materials to develop neutral energetic compounds, whereas research focused on ionic energetic materials obtained from natural bio-renewable frameworks is scarce. This work systematically investigates ionic bio-energetic materials (IBEMs) derived from sustainable natural amino acids. In addition to combustibility, high density, good thermal stability, and one-step preparation, these IBEMs demonstrated apparent hypotoxicity and insensitivity. Moreover, a theoretical examination was performed to explore their appropriate properties. The intriguing results of this study indicates that IBEMs are potential bio-based energetic materials.
含能盐/离子液体作为有前途的能量材料越来越受到关注,而使用可再生化合物是开发能量材料的一种很有前途的方法。直到最近,生物分子才被用作开发中性含能化合物的原料,而研究重点主要集中在从天然生物可再生骨架获得的离子含能材料上。这项工作系统地研究了来源于可持续天然氨基酸的离子生物含能材料(IBEMs)。除了易燃性、高密度、良好的热稳定性和一步制备外,这些 IBEMs 还表现出明显的低毒性和不敏感性。此外,还进行了理论研究以探索它们的适当性质。这项研究的有趣结果表明,IBEMs 是有潜力的基于生物的能量材料。