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少层薄膜金属玻璃增强 ZnO 纳米结构的光学性能。

Few-Layer Thin-Film Metallic Glass-Enhanced Optical Properties of ZnO Nanostructures.

机构信息

Graduate Institute of Electro-Optical Engineering and Department of Electronic and Computer Engineering, National Taiwan University of Science and Technology , Taipei 106, Taiwan.

Department of Materials Science and Engineering, National Taiwan University of Science and Technology , Taipei 10607, Taiwan.

出版信息

ACS Appl Mater Interfaces. 2017 Nov 15;9(45):39475-39483. doi: 10.1021/acsami.7b13121. Epub 2017 Nov 1.

DOI:10.1021/acsami.7b13121
PMID:29064666
Abstract

A few layers of Cu-based (CuZrAlTi) thin-film metallic glasses (TFMGs) were sputtered on hydrothermally synthesized ZnO nanowires/glass and ZnO nanotubes/glass to fabricate UV photodetectors. The few layers of Cu-based TFMG are ultrathin at ∼0.98 nm and have a noncrystalline metal structure according to X-ray diffraction, Raman, photoluminescence, and high-temperature transmission electron microscopy verification. The photoresponse performance of the coated few-layers Cu-TFMG samples was enhanced 1680-7700% compared with the noncoated sample. The few-layers Cu-TFMG has high transmittance ∼90% in the visible band and creates a large capacitor to absorb UV photocurrent and release dark current.

摘要

在水热合成的 ZnO 纳米线/玻璃和 ZnO 纳米管/玻璃上溅射了几层 Cu 基(CuZrAlTi)薄膜金属玻璃(TFMG),以制备紫外光探测器。根据 X 射线衍射、拉曼、光致发光和高温透射电子显微镜验证,Cu 基 TFMG 的几层薄膜非常薄,约为 0.98nm,具有非晶态金属结构。与未镀膜样品相比,镀膜后的几层 Cu-TFMG 样品的光电响应性能提高了 1680-7700%。在可见光波段,几层 Cu-TFMG 的透过率高达 90%,形成大电容,吸收紫外光电流并释放暗电流。

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