College of Life Sciences, Laboratory of Fiber Materials and Modern Textiles, the Growing Base for State Key Laboratory, Qingdao University, Qingdao 266071, China.
Chem Soc Rev. 2018 Jan 22;47(2):586-625. doi: 10.1039/c7cs00500h.
The development of two-dimensional (2D) inorganic materials-based quantum dots (QDs) is still in its infancy but is triggering immense enthusiasm due to their high chemical stability, good aqueous dispersibility, excellent optical property, good biocompatibility and easy functionalization. This review covers almost all the extant 2D-QDs based on graphene, phosphorene, silicene, carbides, nitrides, transition metal dichalcogenide, transition metal oxides and MXenes, etc. Their categories, synthetic routes, properties, functionalization and applications are critically highlighted. In the application section, special emphasis is placed on the progress in bioimaging, cancer therapy, fluorescent sensing and optoelectronics. Meanwhile, the latest advances in 2D QDs-based catalysis and energy since 2015 are addressed. Moreover, 2D nanoclusters, in particular 2D-QDs, are also included. This review provides guidance for 2D-QDs studies to meet the increasing demands in the many diverse applications.
二维(2D)无机材料量子点(QDs)的发展仍处于起步阶段,但由于其化学稳定性高、良好的水分散性、优异的光学性能、良好的生物相容性和易于功能化,引发了巨大的热情。本综述涵盖了几乎所有现有的基于石墨烯、磷烯、硅烯、碳化物、氮化物、过渡金属二卤化物、过渡金属氧化物和 MXenes 等的 2D-QDs。重点介绍了它们的分类、合成路线、性质、功能化和应用。在应用部分,特别强调了在生物成像、癌症治疗、荧光传感和光电子学方面的进展。同时,还介绍了自 2015 年以来基于 2D QDs 的催化和能源领域的最新进展。此外,还包括二维纳米团簇,特别是二维-QDs。本综述为 2D-QDs 的研究提供了指导,以满足许多不同应用中不断增长的需求。