Stability and Performance of CsPbIBr Thin Films and Solar Cell Devices.

In this manuscript, the inorganic perovskite CsPbIBr is investigated as a photovoltaic material that offers higher stability than the organic-inorganic hybrid perovskite materials. It is demonstrated that CsPbIBr does not irreversibly degrade to its component salts as in the case of methylammonium lead iodide but instead is induced (by water vapor) to transform from its metastable brown cubic (1.92 eV band gap) phase to a yellow phase having a higher band gap (2.85 eV). This is easily reversed by heating to 350 °C in a dry environment. Similarly, exposure of unencapsulated photovoltaic devices to water vapor causes current (J) loss as the absorber transforms to its more transparent (yellow) form, but this is also reversible by moderate heating, with over 100% recovery of the original device performance. NMR and thermal analysis show that the high band gap yellow phase does not contain detectable levels of water, implying that water induces the transformation but is not incorporated as a major component. Performances of devices with best efficiencies of 9.08% (V = 1.05 V, J = 12.7 mA cm and FF = 68.4%) using a device structure comprising glass/ITO/c-TiO/CsPbIBr/Spiro-OMeTAD/Au are presented, and further results demonstrating the dependence of the performance on the preparation temperature of the solution processed CsPbIBr films are shown. We conclude that encapsulation of CsPbIBr to exclude water vapor should be sufficient to stabilize the cubic brown phase, making the material of interest for use in practical PV devices.