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柚子皮作为表没食子儿茶素没食子酸酯吸附剂的应用。

The application of pomelo peel as a carrier for adsorption of epigallocatechin-3-gallate.

机构信息

College of Horticulture, Fujian Agriculture and Forestry University, Fuzhou, China.

Key Laboratory of Tea Science in Universities of Fujian Province, Fujian Agriculture and Forestry University, Fuzhou, China.

出版信息

J Sci Food Agric. 2018 Aug;98(11):4135-4141. doi: 10.1002/jsfa.8931. Epub 2018 Mar 12.

Abstract

BACKGROUND

Pomelo (Citrus grandis) is the largest citrus fruit, the peel of which is a well-known agricultural wastes. Disposal of pomelo peel after consumption is a serious environment problem. As a natural, versatile bio-absorbent, pomelo peel has shown excellent adsorption capacity for several pollutants, attributed to its micro-pores; however, there is no relevant report on its adsorption capacity for natural products or food ingredients. The ability of pomelo peel to adsorb epigallocatechin-3-gallate (EGCG) was examined in this study. The physicochemical characterizations of pomelo peel were determined by Fourier transform infrared spectroscopy, scanning electron microscopy and high-performance liquid chromatography. The adsorption process of EGCG onto pomelo peel from aqueous solution was carried out at a range of concentrations (50-800 mg L ) and temperatures (25, 40 and 55 °C).

RESULTS

The main components of pomelo peel are composed of dietary fiber, which provide sufficient adsorption sites during the adsorption process. The adsorption of EGCG onto pomelo peel showed excellent fitness with a pseudo-second-order model. Both Langmuir and Freundlich models were able to describe the isothermal adsorption of EGCG onto pomelo peel. The results of thermodynamic analysis suggested that adsorption is spontaneous and endothermic in nature, and that the process is likely to be dominated by a physisorption mechanism.

CONCLUSION

The results of this study indicate that pomelo peel has potential adsorption capacity for EGCG, which can be used as an effective, low-cost carrier for delivery of natural products in functional food and dietary supplement applications. © 2018 Society of Chemical Industry.

摘要

背景

柚子(Citrus grandis)是最大的柑橘类水果,其果皮是一种众所周知的农业废弃物。消费后柚子皮的处理是一个严重的环境问题。柚子皮作为一种天然、多功能的生物吸附剂,对几种污染物表现出优异的吸附能力,这归因于其微孔;然而,目前还没有关于其对天然产物或食品成分的吸附能力的相关报道。本研究考察了柚子皮对表没食子儿茶素-3-没食子酸酯(EGCG)的吸附能力。通过傅里叶变换红外光谱、扫描电子显微镜和高效液相色谱法对柚子皮的物理化学性质进行了测定。在一系列浓度(50-800mg/L)和温度(25、40 和 55°C)下,从水溶液中进行了 EGCG 吸附到柚子皮上的吸附过程。

结果

柚子皮的主要成分由膳食纤维组成,在吸附过程中提供了足够的吸附位点。EGCG 吸附到柚子皮上表现出极好的拟合度,符合伪二级模型。Langmuir 和 Freundlich 模型都能够描述 EGCG 吸附到柚子皮上的等温吸附。热力学分析的结果表明,吸附是自发和吸热的,该过程可能主要由物理吸附机制控制。

结论

本研究结果表明,柚子皮对 EGCG 具有潜在的吸附能力,可作为功能性食品和膳食补充剂中天然产物有效、低成本载体的应用。 © 2018 化学工业协会。

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