Brubaker Kyle, Garewal Armand, Steinhardt Rachel C, Esser-Kahn Aaron P
Institute of Molecular Engineering, University of Chicago, Chicago, IL, 60637, USA.
Department of Chemistry, University of California - Irvine, Irvine, CA, 92697, USA.
Nat Commun. 2018 Feb 21;9(1):736. doi: 10.1038/s41467-018-03052-y.
Improving the efficiency of gas separation technology is a challenge facing modern industry, since existing methods for gas separation, including hollow-fiber membrane contactors, vacuum swing adsorption, and cryogenic distillation, represents a significant portion of the world's energy consumption. Here, we report an enhancement in the release rate of carbon dioxide and oxygen of a thermal swing gas desorption unit using a counter-current amplification method inspired by fish. Differing from a conventional counter-current extraction system, counter-current amplification makes use of parallel capture fluid channels separated by a semipermeable membrane in addition to the semipermeable membrane separating the capture fluid channel and the gas release channel. The membrane separating the incoming and outgoing fluid channels allows gas that would normally exit the system to remain in the desorption unit. We demonstrate the system using both resistive heating and photothermal heating. With resistive heating, an increase in release rate of 240% was observed compared to an equivalent counter-current extraction system.
提高气体分离技术的效率是现代工业面临的一项挑战,因为现有的气体分离方法,包括中空纤维膜接触器、变压吸附和低温蒸馏,占全球能源消耗的很大一部分。在此,我们报告了一种受鱼类启发的逆流放大方法,该方法提高了热变温气体解吸装置中二氧化碳和氧气的释放速率。与传统的逆流萃取系统不同,逆流放大除了利用半透膜分隔捕获流体通道和气体释放通道外,还利用由半透膜分隔的平行捕获流体通道。分隔进出流体通道的膜使通常会离开系统的气体保留在解吸装置中。我们使用电阻加热和光热加热对该系统进行了演示。在电阻加热情况下,与等效的逆流萃取系统相比,释放速率提高了240%。