Department of Chemistry , Duke University , Durham , North Carolina 27708 , United States.
ACS Nano. 2018 Apr 24;12(4):3689-3698. doi: 10.1021/acsnano.8b00887. Epub 2018 Mar 21.
Materials that retain a high conductivity under strain are essential for wearable electronics. This article describes a conductive, stretchable composite consisting of a Cu-Ag core-shell nanowire felt infiltrated with a silicone elastomer. This composite exhibits a retention of conductivity under strain that is superior to any composite with a conductivity greater than 1000 S cm. This work also shows how the mechanical properties, conductivity, and deformation mechanism of the composite changes as a function of the stiffness of the silicone matrix. The retention of conductivity under strain was found to decrease as the Young's modulus of the matrix increased. This was attributed to void formation as a result of debonding between the nanowire felt and the elastomer. The nanowire composite was also patterned to create serpentine circuits with a stretchability of 300%.
在应变下保持高导电性的材料对于可穿戴电子产品至关重要。本文描述了一种由 Cu-Ag 核壳纳米线毡浸渍硅酮弹性体组成的导电、可拉伸复合材料。该复合材料在应变下的电导率保持性能优于任何电导率大于 1000 S cm 的复合材料。这项工作还展示了复合材料的机械性能、导电性和变形机制如何随硅酮基质的刚度而变化。研究发现,随着基体杨氏模量的增加,应变下的电导率保持率下降。这归因于纳米线毡和弹性体之间脱粘导致的空隙形成。还对纳米线复合材料进行了图案化处理,以创建具有 300%拉伸性的蛇形电路。