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具有高容量和稳定性的用于钠/钾离子电池的三明治状MoS₂@SnO₂@C

Sandwich-like MoS @SnO @C with High Capacity and Stability for Sodium/Potassium Ion Batteries.

作者信息

Chen Zhi, Yin Dangui, Zhang Ming

机构信息

Key Laboratory for Micro/Nano Optoelectronic Devices of Ministry of Education, School of Physics and Electronics, Hunan University, Changsha, 410082, China.

出版信息

Small. 2018 Apr;14(17):e1703818. doi: 10.1002/smll.201703818. Epub 2018 Mar 15.

Abstract

Sandwich-like MoS @SnO @C nanosheets are prepared by facile hydrothermal reactions. SnO nanosheets can attach to exfoliated MoS nanosheets to prevent restacking of adjacent MoS nanosheets, and carbon transformed from polyvinylpyrrolidone is coated on MoS @SnO , forming a sandwich structure to maintain cycling stability. As an anode for sodium-ion batteries, the electrode greatly deliverers a high initial discharge specific capacity of 530 mA h g and maintains at 396 mA h g after 150 cycles at 0.1 A g . Even at a large current density of 1 A g , it can hold 230 mA h g after 450 cycles. Besides, as an anode for K storage, the electrode also shows a discharge capacity of 312 mA h g after 25 cycles at 0.05 A g . This work may provide a new strategy to prepare other composites which can be applied to new kind of rechargeable batteries.

摘要

通过简便的水热反应制备了三明治状的MoS₂@SnO₂@C纳米片。SnO₂纳米片可以附着在剥离的MoS₂纳米片上,以防止相邻MoS₂纳米片的重新堆叠,并且由聚乙烯吡咯烷酮转化而来的碳包覆在MoS₂@SnO₂上,形成三明治结构以保持循环稳定性。作为钠离子电池的阳极,该电极最初可提供高达530 mA h g的高放电比容量,在0.1 A g的电流密度下循环150次后仍保持在396 mA h g。即使在1 A g的大电流密度下,在450次循环后仍可保持230 mA h g的比容量。此外,作为钾存储的阳极,该电极在0.05 A g的电流密度下循环25次后也显示出312 mA h g的放电容量。这项工作可能为制备可应用于新型可充电电池的其他复合材料提供一种新策略。

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