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氮化铟中的直接俄歇复合与密度依赖空穴扩散

Direct Auger recombination and density-dependent hole diffusion in InN.

作者信息

Aleksiejūnas Ramūnas, Podlipskas Žydrūnas, Nargelas Saulius, Kadys Arūnas, Kolenda Marek, Nomeika Kazimieras, Mickevičius Jūras, Tamulaitis Gintautas

机构信息

Institute of Photonics and Nanotechnology, Vilnius University, Saulėtekio ave. 3, Vilnius, LT-10257, Lithuania.

出版信息

Sci Rep. 2018 Mar 15;8(1):4621. doi: 10.1038/s41598-018-22832-6.

Abstract

Indium nitride has a good potential for infrared optoelectronics, yet it suffers from fast nonradiative recombination, the true origin of which has not been established with certainty. The diffusion length of free carriers at high densities is not well investigated either. Here, we study carrier recombination and diffusion using the light-induced transient grating technique in InN epilayers grown by pulsed MOCVD on c-plane sapphire. We show that direct Auger recombination governs the lifetime of carriers at densities above ~10 cm. The measured Auger recombination coefficient is (8 ± 1) × 10 cm. At carrier densities above ~5 × 10 cm, we observe the saturation of Auger recombination rate due to phase space filling. The diffusion coefficient of holes scales linearly with carrier density, increasing from 1 cm/s in low-doped layers at low excitations and up to ~40 cm/s at highest carrier densities. The resulting carrier diffusion length remains within 100-300 nm range, which is comparable to the light absorption depth. This feature is required for efficient carrier extraction in bipolar devices, thus suggesting MOCVD-grown InN as the material fit for photovoltaic and photonic applications.

摘要

氮化铟在红外光电子学方面具有良好的潜力,但其存在快速的非辐射复合问题,其真正起源尚未确定。高密度下自由载流子的扩散长度也未得到充分研究。在此,我们使用光诱导瞬态光栅技术研究了在c面蓝宝石上通过脉冲金属有机化学气相沉积(MOCVD)生长的氮化铟外延层中的载流子复合和扩散。我们表明,直接俄歇复合决定了载流子密度高于约10¹⁸ cm⁻³时的载流子寿命。测得的俄歇复合系数为(8 ± 1)×10⁻³¹ cm⁻⁶ s⁻¹。在载流子密度高于约5×10¹⁸ cm⁻³时,由于相空间填充,我们观察到俄歇复合率饱和。空穴的扩散系数与载流子密度呈线性关系,在低激发下的低掺杂层中从1 cm²/s增加到最高载流子密度下的约40 cm²/s。由此产生的载流子扩散长度保持在100 - 300 nm范围内,这与光吸收深度相当。这一特性是双极器件中有效载流子提取所必需的,因此表明MOCVD生长的氮化铟是适合光伏和光子应用的材料。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a9a5/5854707/f09b4368b6c0/41598_2018_22832_Fig1_HTML.jpg

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