Faculty of Science, Kunming University of Science and Technology, Kunming 650500, China.
Faculty of Mechanical and Electrical Engineering, Kunming University of Science and Technology, Kunming 650500, China.
Phys Rev E. 2018 Feb;97(2-1):022130. doi: 10.1103/PhysRevE.97.022130.
Generally, the efficiency of a heat engine strongly coupled with a heat bath is less than the classical Carnot efficiency. Through a model-independent method, we show that the classical Carnot efficiency is achieved in a strongly coupled quantum heat engine. First, we present the first law of quantum thermodynamics in strong coupling. Then, we show how to achieve the Carnot cycle and the classical Carnot efficiency at strong coupling. We find that this classical Carnot efficiency stems from the fact that the heat released in a nonequilibrium process is balanced by the absorbed heat. We also analyze the restrictions in the achievement of the Carnot cycle. The first restriction is that there must be two corresponding intervals of the controllable parameter in which the corresponding entropies of the work substance at the hot and cold temperatures are equal, and the second is that the entropy of the initial and final states in a nonequilibrium process must be equal. Through these restrictions, we obtain the positive work conditions, including the usual one in which the hot temperature should be higher than the cold, and a new one in which there must be an entropy interval at the hot temperature overlapping that at the cold. We demonstrate our result through a paradigmatic model-a two-level system in which a work substance strongly interacts with a heat bath. In this model, we find that the efficiency may abruptly decrease to zero due to the first restriction, and that the second restriction results in the control scheme becoming complex.
一般来说,与热浴强耦合的热机效率低于经典卡诺效率。通过一种模型无关的方法,我们表明强耦合量子热机可以实现经典卡诺效率。首先,我们给出了强耦合量子热力学第一定律。然后,我们展示了如何在强耦合下实现卡诺循环和经典卡诺效率。我们发现,这种经典的卡诺效率源于非平衡过程中释放的热量被吸收的热量所平衡。我们还分析了实现卡诺循环的限制。第一个限制是,在可控参数的两个相应区间中,工作物质在高温和低温下的相应熵必须相等,第二个限制是,非平衡过程中初始和最终状态的熵必须相等。通过这些限制,我们得到了正功的条件,包括通常的高温应高于低温的条件,以及一个新的条件,即高温的熵间隔必须与低温的熵间隔重叠。我们通过一个范例模型——一个与热浴强相互作用的二能级系统,验证了我们的结果。在这个模型中,我们发现由于第一个限制,效率可能会突然降至零,并且第二个限制导致控制方案变得复杂。