第15族三氯化物ECl与阴离子[Mo Cp (CO) (μ-PH )]的反应；首个具有杂μ,η -PE配体（E = As、Sb）的配合物的合成与表征
Reaction of Group 15 Trichlorides ECl with the Anion [Mo Cp (CO) (μ-PH )] ; Synthesis and Characterization of the First Complexes Featuring a Hetero μ,η -PE ligand (E=As, Sb).
作者信息
Davies John E, Kerr Lesley C, Mays Martin J, Raithby Paul R, Tompkin Peter K, Woods Anthony D
机构信息
Department of Chemistry" Lensfield Road, Cambridge, CB2 1EW, UK, Fax: (+44) 1223-336-362.
出版信息
Angew Chem Int Ed Engl. 1998 Jun 5;37(10):1428-1429. doi: 10.1002/(SICI)1521-3773(19980605)37:10<1428::AID-ANIE1428>3.0.CO;2-3.
An Me PE tetrahedrane framework is seen in complexes 2 a-c (E=P, As, Sb), which are prepared from the appropriate trichlorides and 1 in THF. The structures of the new antimony- and arsenic-containing compounds 2 b and 2 c have been determined-this is the first structural characterization of complexes with μ,η -PE heteroligands from elements of Group 15.
在配合物2 a - c（E = P、As、Sb）中可以看到一个MePE四面体框架，它们是由相应的三氯化物和1在四氢呋喃中制备而成的。新的含锑和含砷化合物2 b和2 c的结构已经确定——这是对来自第15族元素的具有μ,η - PE杂配体的配合物的首次结构表征。
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