铝化学中的叠氮化物-氮腈亚胺类比
The Azide-Nitrilimine Analogy in Aluminum Chemistry.
作者信息
Emig Norbert, Gabbaï François P, Krautscheid Harald, Réau Régis, Bertrand Guy
机构信息
Laboratoire de Chimie de Coordination du CNRS, 205, route de Narbonne, 31077 Toulouse Cédex (France), Fax: (+33) 561 55 30 03.
Anorganisch-chemisches Institut, der Technischen Universität München, Lichtenbergstrasse 4, D-85747 Garching (Germany), Fax: (+49) 89-289-13125.
出版信息
Angew Chem Int Ed Engl. 1998 Apr 20;37(7):989-992. doi: 10.1002/(SICI)1521-3773(19980420)37:7<989::AID-ANIE989>3.0.CO;2-1.
Tetracoordinate aluminum derivatives featuring an AlNNCR fragment are stable and possess a rich structural diversity, as exemplified by the nitrilimines 1 and 2, similar to that observed for the related azides. Compound 1 is the first structurally characterized six-membered AlN heterocycle in which the nitrogen and aluminum centers exhibit different coordination numbers. R=P(NiPr ) ; R'=iBu; E=N, CR.
具有AlNNCR片段的四配位铝衍生物是稳定的，并且具有丰富的结构多样性，如腈亚胺1和2所示，这与相关叠氮化物的情况类似。化合物1是第一个结构表征的六元AlN杂环，其中氮和铝中心表现出不同的配位数。R = P(NiPr ) ；R' = iBu；E = N，CR。
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