在多砧装置中于11吉帕斯卡压力和1500°C条件下高压合成γ-PN：一种由PN四面体和四方PN金字塔构成的具有三维网络结构的二元氮化磷（V）。
High-Pressure Synthesis of γ-P N at 11 GPa and 1500 °C in a Multianvil Assembly: A Binary Phosphorus(V) Nitride with a Three-Dimensional Network Structure from PN Tetrahedra and Tetragonal PN Pyramids.
作者信息
Landskron Kai, Huppertz Hubert, Senker Jürgen, Schnick Wolfgang
机构信息
Department Chemie der Ludwig-Maximilians-Universität 81377 München (Germany) Fax: (+49) 89-2180-7440.
出版信息
Angew Chem Int Ed Engl. 2001 Jul 16;40(14):2643-2645. doi: 10.1002/1521-3773(20010716)40:14<2643::AID-ANIE2643>3.0.CO;2-T.
Abstract
Extreme reaction conditions lead to the synthesis of γ-P N . Its crystal structure, unlike that of the normal pressure modification α-P N , is not exclusively built from PN tetrahedra, but from both PN tetrahedra (blue) and tetragonal PN pyramids (red). A tetragonal PN pyramid structure element has not been observed previously.
摘要
极端反应条件导致了γ-PN的合成。与常压变体α-PN的晶体结构不同，它并非完全由PN四面体构成，而是由PN四面体（蓝色）和四方PN金字塔（红色）共同构成。四方PN金字塔结构单元此前未曾被观察到。
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