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工程化纳米多孔有机骨架稳定裸露的金纳米团簇:一种电荷调制方法。

Engineering nanoporous organic frameworks to stabilize naked Au clusters: a charge modulation approach.

机构信息

College of Chemistry, Nanchang University, Nanchang, China.

出版信息

Chem Commun (Camb). 2018 May 15;54(40):5058-5061. doi: 10.1039/c8cc02966k.

Abstract

A simple charge modulation approach has been developed to stabilize naked Au clusters on a nanoporous conjugated organic network. Through engineering pore walls with regulated charges, the controllable growth of Au nanoclusters has been realized. The resulting supported catalyst exhibits excellent performance in the aerobic oxidation of alcohols.

摘要

一种简单的电荷调制方法被开发出来,用于稳定裸露的金纳米簇在纳米多孔共轭有机网络上。通过工程化具有调节电荷的孔壁,实现了 Au 纳米团簇的可控生长。所得负载型催化剂在醇的有氧氧化中表现出优异的性能。

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