Department of Chemistry, Delta State University, P.M.B. 1, Abraka, Delta State, Nigeria.
Department of Chemistry, Federal University of Petroleum Resources, Efurrun, Delta State, Nigeria.
Ecotoxicol Environ Saf. 2018 Sep 15;159:342-353. doi: 10.1016/j.ecoenv.2018.04.070. Epub 2018 May 21.
The levels of Cd, Pb, Cr, Ni, Cu, Co, Ba, Mn, Zn, Al and Fe were evaluated in indoor dusts from electronic workshops, cybercafés and offices in southern Nigeria. The study was aimed at providing information on the distribution patterns, and the associated risks that may arise from exposure of humans to these metals in indoor dusts from the three work environments. The dust samples were digested with aqua-regia and analyzed for the metal concentrations by inductively coupled plasma-atomic emission spectrometry (ICP-AES). The metal concentrations (mg kg) in the indoor dusts from these work environments ranged from 0.2 to 20.5 Cd, 0.6-4810 Pb, 8.65-2210 Cr, 1.85-209 Ni, 6.75-2820 Cu, 0.25-19.6 Co, 22.7-597 Mn, 6.65-140 Ba, 43.3-7310 Zn, 1040-16,800 Al and 969-78,300 Fe. The metal distribution patterns in these dust samples followed the order: electronic workshops > cybercafés > offices. The concentrations of Cd, Pb and Cu in significant proportions of the dust samples from the electronic workshops and cybercafés surpassed their respective permissible limits in soils. The health risk assessment suggests considerable non-cancer risks arising from childhood contact with Pb in dust from the electronic workshops while no considerable non-cancer risk is associated with the adult and child exposure to dust from the cybercafés and offices. The results indicated that Cr and Pb are the main elements responsible for the non-carcinogenic risk arising from childhood exposure to electronic workshop dusts. The carcinogenic risk due to exposure of humans to metals in these dust samples were within the range regarded as safe by the USEPA.
室内灰尘中 Cd、Pb、Cr、Ni、Cu、Co、Ba、Mn、Zn、Al 和 Fe 的水平在尼日利亚南部的电子车间、网吧和办公室进行了评估。这项研究旨在提供有关分布模式的信息,以及人类在这三种工作环境的室内灰尘中接触这些金属可能带来的相关风险。使用 Aqua-regia 对灰尘样本进行消解,然后通过电感耦合等离子体原子发射光谱仪(ICP-AES)对金属浓度进行分析。这些工作环境室内灰尘中的金属浓度(mg/kg)范围为 0.2-20.5 Cd、0.6-4810 Pb、8.65-2210 Cr、1.85-209 Ni、6.75-2820 Cu、0.25-19.6 Co、22.7-597 Mn、6.65-140 Ba、43.3-7310 Zn、1040-16800 Al 和 969-78300 Fe。这些灰尘样本中的金属分布模式为:电子车间 > 网吧 > 办公室。电子车间和网吧的灰尘样本中 Cd、Pb 和 Cu 的浓度在很大比例上超过了各自土壤的允许限度。健康风险评估表明,儿童接触电子车间灰尘中的 Pb 会带来相当大的非癌症风险,而成年人和儿童接触网吧和办公室的灰尘则没有相当大的非癌症风险。结果表明,Cr 和 Pb 是儿童接触电子车间灰尘时产生非致癌风险的主要元素。人类接触这些灰尘样本中的金属所产生的致癌风险在 USEPA 认为安全的范围内。