Zhang Hui, Toudert Johann
Key Laboratory of Flexible Electronics (KLOFE) and Institute of Advanced Materials (IAM), Jiangsu National Synergetic Innovation Center for Advanced Materials (SICAM), Nanjing Tech University (NanjingTech), Nanjing, P.R. China.
ICFO - Institut de Ciencies Fotoniques, The Barcelona Institute of Science and Technology, Barcelona, Spain.
Sci Technol Adv Mater. 2018 May 24;19(1):411-424. doi: 10.1080/14686996.2018.1458578. eCollection 2018.
In a few years only, solar cells using hybrid organic-inorganic lead halide perovskites as optical absorber have reached record photovoltaic energy conversion efficiencies above 20%. To reach and overcome such values, it is required to tailor both the electrical and optical properties of the device. For a given efficient device, optical optimization overtakes electrical one. Here, we provide a synthetic review of recent works reporting or proposing so-called optical management approaches for improving the efficiency of perovskite solar cells, including the use of anti-reflection coatings at the front substrate surface, the design of optical cavities integrated within the device, the incorporation of plasmonic or dielectric nanostructures into the different layers of the device and the structuration of its internal interfaces. We finally give as outlooks some insights into the less-explored management of the perovskite fluorescence and its potential for enhancing the cell efficiency.
仅在几年内,使用混合有机-无机卤化铅钙钛矿作为光吸收体的太阳能电池就达到了创纪录的超过20%的光伏能量转换效率。为了达到并超越这些数值,需要对器件的电学和光学性质进行调整。对于给定的高效器件,光学优化比电学优化更为重要。在此,我们对最近报道或提出的用于提高钙钛矿太阳能电池效率的所谓光学管理方法进行综合综述,包括在前基板表面使用抗反射涂层、在器件内集成光学腔的设计、将等离子体或介电纳米结构引入器件的不同层以及对其内部界面进行结构化。我们最后展望了一些对钙钛矿荧光较少探索的管理及其提高电池效率潜力的见解。