Zhan Tianzhuo, Yamato Ryo, Hashimoto Shuichiro, Tomita Motohiro, Oba Shunsuke, Himeda Yuya, Mesaki Kohei, Takezawa Hiroki, Yokogawa Ryo, Xu Yibin, Matsukawa Takashi, Ogura Atsushi, Kamakura Yoshinari, Watanabe Takanobu
Faculty of Science and Engineering, Waseda University, TokyoJapan.
Graduate School of Science and Technology, Meiji University, Kawasaki, Japan.
Sci Technol Adv Mater. 2018 May 24;19(1):443-453. doi: 10.1080/14686996.2018.1460177. eCollection 2018.
For harvesting energy from waste heat, the power generation densities and fabrication costs of thermoelectric generators (TEGs) are considered more important than their conversion efficiency because waste heat energy is essentially obtained free of charge. In this study, we propose a miniaturized planar Si-nanowire micro-thermoelectric generator (SiNW-μTEG) architecture, which could be simply fabricated using the complementary metal-oxide-semiconductor-compatible process. Compared with the conventional nanowire μTEGs, this SiNW-μTEG features the use of an exuded thermal field for power generation. Thus, there is no need to etch away the substrate to form suspended SiNWs, which leads to a low fabrication cost and well-protected SiNWs. We experimentally demonstrate that the power generation density of the SiNW-μTEGs was enhanced by four orders of magnitude when the SiNWs were shortened from 280 to 8 μm. Furthermore, we reduced the parasitic thermal resistance, which becomes significant in the shortened SiNW-μTEGs, by optimizing the fabrication process of AlN films as a thermally conductive layer. As a result, the power generation density of the SiNW-μTEGs was enhanced by an order of magnitude for reactive sputtering as compared to non-reactive sputtering process. A power density of 27.9 nW/cm has been achieved. By measuring the thermal conductivities of the two AlN films, we found that the reduction in the parasitic thermal resistance was caused by an increase in the thermal conductivity of the AlN film and a decrease in the thermal boundary resistance.
对于从废热中获取能量而言,热电发电机(TEG)的发电密度和制造成本比其转换效率更为重要,因为废热能基本上是免费获取的。在本研究中,我们提出了一种小型化的平面硅纳米线微型热电发电机(SiNW-μTEG)架构,它可以通过互补金属氧化物半导体兼容工艺简单制造。与传统的纳米线μTEG相比,这种SiNW-μTEG的特点是利用散发的热场来发电。因此,无需蚀刻掉衬底以形成悬空的SiNW,这导致了较低的制造成本以及得到良好保护的SiNW。我们通过实验证明,当SiNW从280μm缩短至8μm时,SiNW-μTEG的发电密度提高了四个数量级。此外,我们通过优化作为导热层的AlN薄膜的制造工艺,降低了在缩短的SiNW-μTEG中变得显著的寄生热阻。结果,与非反应溅射工艺相比,反应溅射使SiNW-μTEG的发电密度提高了一个数量级。已经实现了27.9 nW/cm的功率密度。通过测量两种AlN薄膜的热导率,我们发现寄生热阻的降低是由AlN薄膜热导率的增加和热边界电阻的降低引起的。