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(2,2')-3,3'-(1,4-亚苯基)双-[1-(4-羟基苯基)丙-2-烯-1-酮] - 二甲基甲酰胺溶剂化物的合成、光谱和 Hirshfeld 表面分析以及荧光研究

Synthesis, spectroscopic and Hirshfeld surface analysis and fluorescence studies of (2,2')-3,3'-(1,4-phenyl-ene)bis-[1-(4-hy-droxy-phen-yl)prop-2-en-1-one] ,-di-methyl-formamide disolvate.

作者信息

Kwong Huey Chong, Sim Ai Jia, Chidan Kumar C S, Quah Ching Kheng, Chantrapromma Suchada, Naveen S, Warad Ismail

机构信息

School of Chemical Sciences, Universiti Sains Malaysia, Penang 11800 USM, Malaysia.

X-ray Crystallography Unit, School of Physics, Universiti Sains Malaysia, 11800 USM, Penang, Malaysia.

出版信息

Acta Crystallogr E Crystallogr Commun. 2018 May 22;74(Pt 6):835-839. doi: 10.1107/S2056989018007429. eCollection 2018 Jun 1.

Abstract

In the bis-chalcone mol-ecule of the title compound, CHO·2CHNO, the central benzene and terminal hy-droxy-phenyl rings form a dihedral angle of 14.28 (11)° and the central C=C double bond adopts a configuration. In the crystal, the bis-chalcone and solvate mol-ecules are inter-connected O-H⋯O hydrogen bonds, which were investigated by Hirshfeld surface analysis. Solid-state fluorescence was measured at λ = 4400 Å. The emission wavelength appeared at 5510 Å, which corresponds to yellow light and the solid-state fluorescence quantum yield () is 0.18.

摘要

在标题化合物CHO·2CHNO的双查尔酮分子中,中心苯环和末端羟基苯环形成的二面角为14.28 (11)°,中心C=C双键呈 构型。在晶体中,双查尔酮和溶剂化物分子通过O-H⋯O氢键相互连接,通过 Hirshfeld 表面分析对其进行了研究。在λ = 4400 Å处测量了固态荧光。发射波长出现在5510 Å处,对应于黄光,固态荧光量子产率()为0.18。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d121/6002815/91a121d23b1d/e-74-00835-fig1.jpg

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