Patra Puneet Kumar, Bhattacharya Baidurya
Department of Civil Engineering, Indian Institute of Technology Kharagpur, Kharagpur, 721302, India.
Sci Rep. 2018 Aug 3;8(1):11670. doi: 10.1038/s41598-018-30129-x.
The Zeroth Law implies that the three systems, each separately in equilibrium and having the same temperature, must remain so when brought in pairwise or simultaneous thermal contact with each other. We examine numerically the conformity of the logarithmic thermostat with the Zeroth Law of thermodynamics. Three specific scenarios, with different heat reservoirs, are investigated. For each scenario, the system of interest, S - a single harmonic oscillator, is coupled with two heat reservoirs, S and S. S and S are variously chosen to be from the Nosé-Hoover, the Hoover-Holian, the C and the logarithmic thermostats. In the scenarios involving logarithmic thermostat, we observe a violation of the Zeroth Law of thermodynamics, in computationally achievable time, at low to moderate coupling strengths: (i) the kinetic and configurational temperatures of the systems are different, (ii) momentum distribution of log thermostat is non-Gaussian, and (iii) a temperature gradient is created between the kinetic and configurational variables of the log thermostat.
第零定律表明,这三个系统各自处于平衡状态且具有相同的温度,当它们两两或同时进行热接触时,必须保持这种状态。我们通过数值方法研究对数恒温器与热力学第零定律的符合程度。研究了三种不同热库的具体情况。对于每种情况,感兴趣的系统S——一个单谐振子,与两个热库S₁和S₂耦合。S₁和S₂分别从诺思 - 胡佛、胡佛 - 霍利安、C和对数恒温器中进行各种选择。在涉及对数恒温器的情况下,我们发现在低至中等耦合强度下,在可计算的时间内违反了热力学第零定律:(i)系统的动力学温度和构型温度不同,(ii)对数恒温器的动量分布是非高斯的,(iii)在对数恒温器的动力学变量和构型变量之间产生了温度梯度。