School of Environmental and Municipal Engineering, Xi'an University of Architecture and Technology, Xi'an, 710055, People's Republic of China.
School of Human Settlements and Civil Engineering, Xi'an Jiaotong University, Xi'an, 710049, People's Republic of China.
Environ Monit Assess. 2018 Aug 16;190(9):524. doi: 10.1007/s10661-018-6901-2.
Blended water, always existing in a drinking water distribution system (DWDS) with different sources, can cause some unintended results, including corrosion and/or release of corrosion by-products. Although some studies have specially focused on the blended water in DWDSs, the water quality characteristics, variations, and mechanisms for corrosion and metal release have not been fully understood. This study aims to examine the characteristics and evaluate the corrosion potential of blended water in X city DWDS using four indices of Langelier saturation index (LSI), Ryznar stability index (RSI), Puckorius scaling index (PSI), and calcium carbonate precipitation potential (CCPP). Physical and chemical analysis showed that the values of pH, total dissolved solids (TDS), sulfate (SO), and chloride (Cl) in blended water were always at acceptable levels, while some free residual chlorine concentrations fell outside the regulatory standards (≥ 0.05 mg/L) with the minimum of 0.01 mg/L. Most parameters except pH varied in large ranges with maximum to minimum ratios (MMRs) over 2.25. The mean values of the LSI, RSI, PSI, and CCPP indices were - 0.44, 8.65, 8.79, and - 1.95 mg/L CaCO, respectively, indicating that the blended water was slightly corrosive. For the three zones, Z2 had the highest mean levels of TDS (320.84 mg/L), alkalinity (188.70 mg/L CaCO), SO (13.69 mg/L), Cl (36.37 mg/L), calcium hardness (Ca) (28.99 mg/L), and magnesium hardness (Mg) (15.22 mg/L) and the lowest mean level of dissolved oxygen (DO) (6.72 mg/L). Thus, the corrosion potential in Z2 was the lowest with the LSI, RSI, PSI, and CCPP values of - 0.17, 8.11, 8.08, and 2.87 mg/L CaCO, respectively. During a year, the corrosion in blended water was more serious in winter with the LSI, RSI, PSI, and CCPP indices of - 0.79, 9.25, 9.37, - 7.54 mg/L CaCO, respectively. The water corrosivity reached the minimum level in summer (LSI - 0.12, RSI 8.05, PSI 8.03, and CCPP 5.22 mg/L CaCO) owing to the decrease of DO concentrations and the increase of temperature and groundwater supplies with higher alkalinity. During rainy season, the concentrations of TDS, alkalinity, SO, Cl, Ca, and Mg in blended water were reduced by 41.05%, 40.48%, 35.83%, 47.48%, 23.47%, and 55.73%, respectively, resulting in the increase of water corrosivity. More decreases of water parameters were recorded in Z2 (TDS, 221.80 mg/L; alkalinity, 139.50 mg/L CaCO; SO, 9.97 mg/L; Cl, 13.74 mg/L; Ca, 7.10 mg/L; and Mg, 11.37 mg/L), because most groundwater from No. 5 WTP was pumped paretic water with more variations of water quality by rainfall. Moreover, it was suggested that Mg should be considered in the corrosion indices, and the corrosion tendency of blended water could be reduced by adjusting the levels of pH, alkalinity, Ca, and Mg. The results of this research may pave the way for several opportunities to improve the management and corrosion prevention of blended water.
混合水在饮用水分配系统(DWDS)中始终存在,其来源不同,可能会导致一些意想不到的结果,包括腐蚀和/或腐蚀产物的释放。尽管一些研究专门针对 DWDS 中的混合水进行了研究,但腐蚀和金属释放的水质特性、变化和机制尚未完全了解。本研究旨在使用朗格利尔饱和度指数(LSI)、赖兹纳稳定性指数(RSI)、普克留斯结垢指数(PSI)和碳酸钙沉淀潜力(CCPP)四个指标来考察 X 市 DWDS 中混合水的特性并评估其腐蚀潜力。理化分析表明,混合水中的 pH 值、总溶解固体(TDS)、硫酸盐(SO)和氯化物(Cl)的含量始终处于可接受的水平,而一些自由余氯浓度低于(≥0.05mg/L)规定标准,最低为 0.01mg/L。除 pH 值外,大多数参数的变化范围较大,最大值与最小值之比(MMR)超过 2.25。LSI、RSI、PSI 和 CCPP 指数的平均值分别为-0.44、8.65、8.79 和-1.95mg/L CaCO3,表明混合水略具腐蚀性。对于三个区域,Z2 具有最高的 TDS(320.84mg/L)、碱度(188.70mg/L CaCO3)、SO(13.69mg/L)、Cl(36.37mg/L)、钙硬度(Ca)(28.99mg/L)和镁硬度(Mg)(15.22mg/L)的平均值,以及最低的溶解氧(DO)(6.72mg/L)平均值。因此,Z2 的腐蚀潜力最低,LSI、RSI、PSI 和 CCPP 值分别为-0.17、8.11、8.08 和 2.87mg/L CaCO3。在一年中,冬季混合水中的腐蚀更为严重,LSI、RSI、PSI 和 CCPP 指数分别为-0.79、9.25、9.37 和-7.54mg/L CaCO3。由于 DO 浓度降低、温度升高以及高碱度的地下水供应增加,夏季的水腐蚀性达到最低水平(LSI-0.12、RSI8.05、PSI8.03 和 CCPP5.22mg/L CaCO3)。在雨季,混合水中的 TDS、碱度、SO、Cl、Ca 和 Mg 浓度分别降低了 41.05%、40.48%、35.83%、47.48%、23.47%和 55.73%,导致水腐蚀性增加。Z2 中记录了更多的水参数下降(TDS,221.80mg/L;碱度,139.50mg/L CaCO3;SO,9.97mg/L;Cl,13.74mg/L;Ca,7.10mg/L;和 Mg,11.37mg/L),因为大多数来自 5 号自来水厂的地下水是在降雨时抽取的水质变化较大的 Paretic 水。此外,建议在腐蚀指数中考虑 Mg,并通过调整 pH 值、碱度、Ca 和 Mg 的水平来降低混合水的腐蚀趋势。本研究的结果可能为改善混合水的管理和腐蚀预防提供一些机会。