Chemical Engineering Department, King Saud University, Riyadh, Saudi Arabia.
Mechanical Engineering department, King Saud University, Riyadh, Saudi Arabia.
PLoS One. 2018 Oct 9;13(10):e0205012. doi: 10.1371/journal.pone.0205012. eCollection 2018.
Desalination of geothermal brackish water by membrane distillation (MD) provides a low recovery rate, but integrating MD with reverse osmosis (RO) can maximize the production rate. In this study, different design configurations of a hybrid system involving brine recycling and cascading are studied via simulations, and the performance improvement due to the process integration is substantiated via the increased recovery rate and reduced specific energy consumption. Brine recycling is also found to improve the recovery rate considerably to 40% at an energy cost of 0.9 $/m3. However, this achievement is only valid when the final brine is recycled to the RO feed: when the final brine is recycled to the MD feed, the overall performance degrades because the recycled brine cools the feed and causes a serious reduction in the driving force and the consequent production rate. Configuring the hybrid system in multiple stages connected in series increases the recovery rate to 90% and reduces the specific energy consumption to 0.9 MJ/kg. Although the specific energy cost increases dramatically because external inter-stage heating is implemented, using a free energy source (such as a geothermal or waste-energy source) for inter-stage heating could provide the optimum configuration.
膜蒸馏(MD)脱除地热苦咸水的回收率较低,但将 MD 与反渗透(RO)集成可以最大限度地提高产率。本研究通过模拟研究了涉及盐水再循环和级联的混合系统的不同设计配置,并通过提高回收率和降低比能耗来证实了由于过程集成而带来的性能提升。盐水再循环也将回收率提高到 40%,能耗为 0.9 美元/立方米。然而,只有当最终盐水被回收到 RO 进料中时,这一结果才有效:当最终盐水被回收到 MD 进料中时,整体性能会恶化,因为再循环盐水会冷却进料并导致驱动力严重降低,从而导致产率降低。将混合系统配置为多个串联连接的级联可以将回收率提高到 90%,并将比能耗降低至 0.9MJ/kg。尽管由于实施了外部级间加热,比能耗成本会大幅增加,但使用自由能源(如地热能或废热能源)进行级间加热可以提供最佳配置。