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基于碳材料的增强型剩余活性污泥电脱水用于同步燃料处理。

Carbon-based materials reinforced waste activated sludge electro-dewatering for synchronous fuel treatment.

机构信息

University of Chinese Academy of Science, Beijing, 100085, China; State Key Laboratory of Environmental Aquatic Chemistry, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing, 100085, China.

State Key Laboratory of Environmental Aquatic Chemistry, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing, 100085, China.

出版信息

Water Res. 2019 Feb 1;149:533-542. doi: 10.1016/j.watres.2018.10.082. Epub 2018 Oct 31.

Abstract

Sludge treatment and disposal have become critical environmental issues in China. Electro-dewatering (ED) is an attractive technology for enhancing dewaterability and improving the sustainability of waste activated sludge (WAS) handling. However, electrically assisted mechanical dewatering processes consume more energy and the extracellular polymeric substance (EPS) dissolution caused by electrochemical reactions can lead to clogging of the filter cloth. Carbon-based materials (CBMs) such as activated carbon and graphite have electrical conductivity and well-developed pore structures which can adsorb the biopolymers. Therefore, addition of CBMs is expected to improve WAS electro-dewatering performance for fuel treatment by enhancing sludge conductivity and filterability. In this study, we evaluated the effects of the three carbon materials (AC-0, AC-5, and graphite) on sludge electro-dewatering behavior and the flammability of sludge cakes. The results showed that CBMs promote the performance of WAS electro-dewatering, and the promoting effect of the carbon materials on the sludge electro-dewatering is proportional to the electrical conductivity of the carbon material, and carbon materials can increase the electrophoretic mobility of sludge flocs and the electro-osmotic effect. Moreover, CBMs can adsorb the dissolved EPS, thus alleviate the plugging and filtration resistance of the filter medium. The addition of CBMs also decreases the energy consumption for water removal during the electro-dewatering process and improves the calorific value and sustainable combustion time of the sludge cake. Our approach can facilitate the resource utilization of the dewatered sludge cake in electro-dewatering processes.

摘要

污泥处理和处置已成为中国的一个关键环境问题。电脱水(ED)是一种提高脱水性能和改善废活性污泥(WAS)处理可持续性的有吸引力的技术。然而,电辅助机械脱水过程消耗更多的能量,并且电化学反应引起的细胞外聚合物(EPS)溶解会导致滤布堵塞。碳基材料(CBMs)如活性炭和石墨具有导电性和发达的孔结构,可以吸附生物聚合物。因此,添加 CBMs 有望通过提高污泥导电性和过滤性来改善 WAS 电脱水性能,以用于燃料处理。在这项研究中,我们评估了三种碳材料(AC-0、AC-5 和石墨)对污泥电脱水行为和污泥饼可燃性的影响。结果表明,CBMs 促进了 WAS 电脱水的性能,碳材料对污泥电脱水的促进作用与碳材料的电导率成正比,并且碳材料可以增加污泥絮体的电泳迁移率和电动效应。此外,CBMs 可以吸附溶解的 EPS,从而减轻过滤介质的堵塞和过滤阻力。添加 CBMs 还可以减少电脱水过程中去除水分所需的能量,并提高污泥饼的热值和可持续燃烧时间。我们的方法可以促进电脱水过程中脱水污泥饼的资源利用。

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