Doku George N, Bortey Emmanuel A
Department of Pharmaceutical Sciences, Central University, P.O. Box 2305, Miotso, Tema, Ghana.
Ghana Med J. 2018 Sep;52(3):163-167. doi: 10.4314/gmj.v52i3.10.
The analysis sought to verify the presence or otherwise and the concentration levels of iodine in the claimed iodated salts on the Ghanaian market.
Eleven (11) most patronized brands of salts, including both local and foreign brands and the raw-pellet salt (crystallized directly from sea water), were obtained from popular shops and markets in Accra. These were analysed both qualitatively and quantitatively by titrimetry, involving the iodate-iodide reaction in acid medium that generates molecular iodine (IO + I+ 6H → I + 3HO).
The iodine content (in ppm) at retail, recorded for the samples are as follows: Sample A (25.4), B (51.8), C (52.9), D (45.5), E (25.4), F (75.1), G (28.6), H (0), I (13.7), J (34.9) and K (16.9). No iodine was observed in the raw-pellet salt (sample H) crystallized directly from sea water, in contrast to the long-held belief that it contains natural iodine. Furthermore, all samples analyzed did not meet the concentration levels indicated on their labels and did not meet the Ghana Standard Authority's standard.
Only samples B and C were close to the Ghana Standard Authority's specification. The Ghana Standard Authority's standard of 100ppm at production and 50ppm at retail may be too high or, probably, the salt iodination companies are not adhering to the rules. The authors therefore recommend that the regulatory authorities (The Food and Drugs Authority and The Ghana Standard Authority) regularize their regulatory activities and educate the public appropriately.
The study was self-funded by the researchers/authors.
该分析旨在验证加纳市场上声称加碘的盐中碘的存在与否及其浓度水平。
从阿克拉的热门商店和市场获取了11个最受青睐的盐品牌,包括本地和外国品牌以及粗盐颗粒(直接从海水中结晶而成)。通过滴定法对这些盐进行了定性和定量分析,该方法涉及在酸性介质中碘酸盐 - 碘化物反应生成分子碘(IO₃⁻ + 5I⁻ + 6H⁺ → 3I₂ + 3H₂O)。
所记录的样品零售时的碘含量(以ppm计)如下:样品A(25.4)、B(51.8)、C(52.9)、D(45.5)、E(25.4)、F(75.1)、G(28.6)、H(0)、I(13.7)、J(34.9)和K(16.9)。直接从海水中结晶的粗盐颗粒(样品H)中未观察到碘,这与长期以来认为其含有天然碘的观点相反。此外,所有分析的样品均未达到其标签上标明的浓度水平,也未达到加纳标准管理局的标准。
只有样品B和C接近加纳标准管理局的规格。加纳标准管理局规定的生产时100ppm和零售时50ppm的标准可能过高,或者盐碘化公司可能未遵守规定。因此,作者建议监管当局(食品药品管理局和加纳标准管理局)规范其监管活动并对公众进行适当教育。
该研究由研究人员/作者自筹资金。