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近期开发的碳水化合物衍生有机凝胶剂及相应的功能性凝胶

Carbohydrate Derived Organogelators and the Corresponding Functional Gels Developed in Recent Time.

作者信息

Basu Nabamita, Chakraborty Arijit, Ghosh Rina

机构信息

Department of Chemistry, Nabagram Hiralal Paul College, Konnagar, West Bengal 712246, India.

Department of Chemistry, Acharya B. N. Seal College, Cooch Behar, West Bengal 736101, India.

出版信息

Gels. 2018 May 30;4(2):52. doi: 10.3390/gels4020052.

DOI:10.3390/gels4020052
PMID:30674828
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC6209255/
Abstract

Owing to their multifarious applicability, studies of molecular and supramolecular gelators and their corresponding gels have gained momentum, particularly in the last two decades. Hydrophobic⁻hydrophilic balance, different solvent parameters, gelator⁻gelator and gelator⁻solvent interactions, including different noncovalent intermolecular interactive forces like H-bonding, ionic interactions, π⁻π interactions, van der Waals interactions, etc., cause the supramolecular gel assembly of micro and nano scales with different types of morphologies, depending on the gelator, solvent, and condition of gelation. These gel structures can be utilized for making template inorganic superstructures for potential application in separation, generation of nanocomposite materials, and other applications like self-healing, controlled drug encapsulation, release and delivery, as structuring agents, oil-spill recovery, for preparation of semi-conducting fabrics, and in many other fields. Sugars, being easily available, inexpensive, and nontoxic natural resources with multi functionality and well-defined chirality are attractive starting materials for the preparation of sugar-based gelators. This review will focus on compilation of sugar derived organogelators and the corresponding gels, along with the potential applications that have been developed and published recently between January 2015 and March 2018.

摘要

由于其多方面的适用性,分子和超分子凝胶剂及其相应凝胶的研究发展迅速,尤其是在过去二十年中。疏水-亲水平衡、不同的溶剂参数、凝胶剂-凝胶剂和凝胶剂-溶剂相互作用,包括不同的非共价分子间相互作用,如氢键、离子相互作用、π-π相互作用、范德华相互作用等,会导致形成具有不同形态的微米和纳米级超分子凝胶聚集体,这取决于凝胶剂、溶剂和凝胶化条件。这些凝胶结构可用于制备模板无机超结构,潜在应用于分离、纳米复合材料的生成以及其他应用,如自愈、可控药物包封、释放和递送、作为结构剂、溢油回收、用于制备半导体织物以及许多其他领域。糖类作为容易获得、价格低廉且无毒的天然资源,具有多功能性和明确的手性,是制备糖基凝胶剂的有吸引力的起始原料。本综述将重点介绍2015年1月至2018年3月期间已开发并发表的糖衍生有机凝胶剂及其相应凝胶,以及潜在应用。

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Chemosphere. 2018 Mar;194:837-846. doi: 10.1016/j.chemosphere.2017.11.103. Epub 2017 Nov 20.
9
A Library of Multipurpose Supramolecular Supergelators: Fabrication of Structured Silica, Porous Plastics, and Fluorescent Gels.多功能超分子超级凝胶剂文库:结构化二氧化硅、多孔塑料和荧光凝胶的制备
Chem Asian J. 2018 Jan 18;13(2):187-193. doi: 10.1002/asia.201701657. Epub 2017 Dec 20.
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Synthesis and gelation property of a series of disaccharide triazole derivatives.一系列二糖三唑衍生物的合成与凝胶化性质
Carbohydr Res. 2017 Nov 8;451:81-94. doi: 10.1016/j.carres.2017.09.008. Epub 2017 Sep 15.