Basu Nabamita, Chakraborty Arijit, Ghosh Rina
Department of Chemistry, Nabagram Hiralal Paul College, Konnagar, West Bengal 712246, India.
Department of Chemistry, Acharya B. N. Seal College, Cooch Behar, West Bengal 736101, India.
Gels. 2018 May 30;4(2):52. doi: 10.3390/gels4020052.
Owing to their multifarious applicability, studies of molecular and supramolecular gelators and their corresponding gels have gained momentum, particularly in the last two decades. Hydrophobic⁻hydrophilic balance, different solvent parameters, gelator⁻gelator and gelator⁻solvent interactions, including different noncovalent intermolecular interactive forces like H-bonding, ionic interactions, π⁻π interactions, van der Waals interactions, etc., cause the supramolecular gel assembly of micro and nano scales with different types of morphologies, depending on the gelator, solvent, and condition of gelation. These gel structures can be utilized for making template inorganic superstructures for potential application in separation, generation of nanocomposite materials, and other applications like self-healing, controlled drug encapsulation, release and delivery, as structuring agents, oil-spill recovery, for preparation of semi-conducting fabrics, and in many other fields. Sugars, being easily available, inexpensive, and nontoxic natural resources with multi functionality and well-defined chirality are attractive starting materials for the preparation of sugar-based gelators. This review will focus on compilation of sugar derived organogelators and the corresponding gels, along with the potential applications that have been developed and published recently between January 2015 and March 2018.
由于其多方面的适用性,分子和超分子凝胶剂及其相应凝胶的研究发展迅速,尤其是在过去二十年中。疏水-亲水平衡、不同的溶剂参数、凝胶剂-凝胶剂和凝胶剂-溶剂相互作用,包括不同的非共价分子间相互作用,如氢键、离子相互作用、π-π相互作用、范德华相互作用等,会导致形成具有不同形态的微米和纳米级超分子凝胶聚集体,这取决于凝胶剂、溶剂和凝胶化条件。这些凝胶结构可用于制备模板无机超结构,潜在应用于分离、纳米复合材料的生成以及其他应用,如自愈、可控药物包封、释放和递送、作为结构剂、溢油回收、用于制备半导体织物以及许多其他领域。糖类作为容易获得、价格低廉且无毒的天然资源,具有多功能性和明确的手性,是制备糖基凝胶剂的有吸引力的起始原料。本综述将重点介绍2015年1月至2018年3月期间已开发并发表的糖衍生有机凝胶剂及其相应凝胶,以及潜在应用。