Department of Materials Science and Metallurgical Engineering, Kyungpook National University, Deagu 41566, Korea.
Surface-Finishing and Fastening Technology Team, Material Development Center, Hyundai Motor Company, Hwaseong 18280, Korea.
J Nanosci Nanotechnol. 2019 Jul 1;19(7):4282-4286. doi: 10.1166/jnn.2019.16277.
In this study, the effects of etching time and temperature on the adhesion of plated layers of acrylonitrile butadiene styrene (ABS) were investigated. The ABS surface micropores, which act as anchors to improve the adhesion of the plated layer, increased in numbers as the etching temperature increased. Adhesion was maximum at the etching time of 9 min at etching temperatures of 60 and 70 °C. For the etching times of 12 and 15 min, micropores on the ABS surface were incompletely filled during electroplating because the pores were both deep and narrow. The adhesion strength was decreased by these unfilled micropores, which further reduced the anchor effect. The ratio of the increased surface area ratio of the ABS to that of the plated surface was maximized at 9 min etching time, at which point the plating adhesion was also maximized.
在这项研究中,考察了蚀刻时间和温度对丙烯腈-丁二烯-苯乙烯(ABS)电镀层附着力的影响。随着蚀刻温度的升高,作为提高镀层附着力的锚固点的 ABS 表面微孔数量增加。在 60 和 70°C 的蚀刻温度下,蚀刻时间为 9 分钟时,附着力最大。对于 12 和 15 分钟的蚀刻时间,由于孔又深又窄,在电镀过程中 ABS 表面的微孔没有完全填满。这些未填满的微孔降低了附着力强度,进一步降低了锚固效果。在 9 分钟的蚀刻时间下,ABS 的表面积增加率与电镀表面的表面积增加率之比最大,此时电镀附着力也最大。