手性铁(ii)基金属有机纳米管：受限通道中的变磁性和选择性一氧化氮吸附
Homochiral iron(ii)-based metal-organic nanotubes: metamagnetism and selective nitric oxide adsorption in a confined channel.
机构信息
State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Collaborative Innovation Center of Advanced Microstructures, Nanjing University, Nanjing 210023, P. R. China.
出版信息
Chem Commun (Camb). 2019 Feb 28;55(19):2825-2828. doi: 10.1039/c9cc00506d.
Homochiral iron(ii)-based nanotubular metal phosphonates (R)- and (S)-[Fe(pemp)(H2O)2] [pemp2- = (R)- or (S)-(1-phenylethylamino)methylphosphonate] are reported showing metamagnetism at low temperature. The dehydrated product features coordinatively unsaturated and redox-active metal ion sites that enable it to strongly bind nitric oxide at room temperature.
手性铁（II）基纳米管状金属膦酸盐（R）-和（S）-[Fe（pemp）（H2O）2] [pemp2- = （R）-或（S）-（1-苯乙基氨基）甲基膦酸酯]被报道在低温下表现出反铁磁性。脱水产物具有配位不饱和和氧化还原活性的金属离子位点，使其能够在室温下强烈结合一氧化氮。
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